Results 161 to 170 of about 35,734 (288)

Mechanistic and Reactivity Insights into Diboron‐Mediated NN and NN Bond Scission

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights the emerging ability of diboron reagents to cleave both π‐bonded (N=N) and σ‐bonded (N—N) nitrogen–nitrogen linkages, integrating mechanistic understanding with recent synthetic applications. Diboron reagents have emerged as versatile reducing agents capable of transforming a broad range of functional groups through pathways like
Raúl Valderrama‐Callejón   +2 more
wiley   +1 more source

Well‐Defined Anilido–Imine Iron(II) Complexes for Catalytic Intramolecular Alkene Hydroamination of Primary Amines

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
We synthesize and characterize a series of well‐defined anilido–imine Fe(II) alkyl complexes that demonstrate high activity and selectivity in the cyclohydroamination of unprotected primary amines tethered to unactivated alkenes. By tuning the steric and electronic parameters of the anilido–imine ligand, we develop a catalyst that outperforms ...
Hui Dong   +5 more
wiley   +1 more source

Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis. [PDF]

open access: yesAngew Chem Int Ed Engl
Escudero J   +12 more
europepmc   +1 more source

Biobased Epoxidized Castor Oil Covalent Adaptable Networks Adhesives Reinforced with Recycled Carbon Fibers

open access: yesMacromolecular Rapid Communications, EarlyView.
It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai   +6 more
wiley   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Hydrocarbon Frameworks with Long-Range Order Synthesized via Olefin Metathesis. [PDF]

open access: yesJ Am Chem Soc
Sui X   +14 more
europepmc   +1 more source

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