Results 201 to 210 of about 42,464 (282)

Toward vanadium-mediated alkyne metathesis. [PDF]

open access: yesChem Sci
Hernandez S   +4 more
europepmc   +1 more source

Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis. [PDF]

open access: yesAngew Chem Int Ed Engl
Escudero J   +12 more
europepmc   +1 more source

Amide‐Enabled Reversal of Regioselectivity in Carbonyl‐Substituted Allenes

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 20, 16 October 2026.
A substrate‐embedded secondary amide reverses the inherent regioselectivity of carbonyl‐substituted allenes, enabling rhodium‐catalyzed α‐acyloxylation with carboxylic acids. This redox‐neutral method requires no external oxidants or auxiliary‐type directing groups and tolerates diverse carboxylic acids.
Naoki Hikida   +3 more
wiley   +1 more source

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

open access: yesAngewandte Chemie, Volume 138, Issue 42, 12 October 2026.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne   +9 more
wiley   +2 more sources

Synthesis and Polymerization of a Lactone Building Block Derived From Cashew Nut Shells

open access: yesChemSusChem, Volume 19, Issue 19, 14 October 2026.
Cardanol as a renewable substituted phenol feedstock was selectively transformed into the corresponding cyclohexanone derivative by means of a partial metal‐catalyzed hydrogenation. Subsequent conversion via Baeyer–Villiger oxidation gave a lactone product consisting of a mixture of regioisomers, which has been readily converted into its homopolymer ...
Paulo R. Wohlfahrt   +6 more
wiley   +1 more source

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