Toward vanadium-mediated alkyne metathesis. [PDF]
Hernandez S +4 more
europepmc +1 more source
Conversion of trifluoromethyls into esters along with polyether upcycling <i>via</i> cation-transfer-catalyzed C-O/C-F metathesis. [PDF]
Li Z, Shi X, Zhang D, Wu Q.
europepmc +1 more source
Kinetic resolution of racemic planar-chiral vinylcymantrenes by molybdenum-catalyzed asymmetric metathesis dimerization. [PDF]
Imazu H, Izu H, Ohki Y, Ogasawara M.
europepmc +1 more source
Divergent and programmable skeletal remodeling of complex macrocycles with a small method set. [PDF]
Nikbakht A +4 more
europepmc +1 more source
Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis. [PDF]
Escudero J +12 more
europepmc +1 more source
Amide‐Enabled Reversal of Regioselectivity in Carbonyl‐Substituted Allenes
A substrate‐embedded secondary amide reverses the inherent regioselectivity of carbonyl‐substituted allenes, enabling rhodium‐catalyzed α‐acyloxylation with carboxylic acids. This redox‐neutral method requires no external oxidants or auxiliary‐type directing groups and tolerates diverse carboxylic acids.
Naoki Hikida +3 more
wiley +1 more source
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne +9 more
wiley +2 more sources
Isolation of ROMP-Generated Macrocyclic Polyalkenamers via Polar Monomer Incorporation and Chain-End Modification. [PDF]
Gan Q +6 more
europepmc +1 more source
Synthesis and Polymerization of a Lactone Building Block Derived From Cashew Nut Shells
Cardanol as a renewable substituted phenol feedstock was selectively transformed into the corresponding cyclohexanone derivative by means of a partial metal‐catalyzed hydrogenation. Subsequent conversion via Baeyer–Villiger oxidation gave a lactone product consisting of a mixture of regioisomers, which has been readily converted into its homopolymer ...
Paulo R. Wohlfahrt +6 more
wiley +1 more source

