Results 211 to 220 of about 35,734 (288)

A Crystalline Ylide‐Stabilized Stibenium Cation

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 17, 17 June 2026.
The isolation of a stibenium cation stabilized by two thiophosphinoyl‐tethered ylide groups is reported. The cation is accessible via salt metathesis of the metalated ylide with SbCl3 and features CSb single bonds, with lone pairs remaining localized at the ylidic carbon atoms.
Daniel Knyszek   +4 more
wiley   +1 more source

Mild N‑Arylation of Sulfoximines With (Hetero)aryl Chlorides Enabled by α‐Methylnaphthyl‐tBuBrettPhos Palladium Triflate

open access: yesChemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
A readily accessible, air‐ and moisture‐stable palladium precatalyst, [Pd(1‐MeNAP)(tBuBrettPhos)]OTf, enables the direct N‐arylation of NH‐sulfoximines with (hetero)aryl chlorides under exceptionally mild conditions ideal for late‐stage diversification of drug‐like scaffolds.
Sourav Manna   +5 more
wiley   +1 more source

Total Synthesis of Scandine. [PDF]

open access: yesJACS Au
Kitamura T   +3 more
europepmc   +1 more source

Activity and stereoselectivity of Ru-based catalyst bearing a fluorinated imidazolinium ligand

open access: yesOpen Chemistry, 2011
Siano Vincenzo   +4 more
doaj   +1 more source

Hydrogen Isotope Exchange in Pyridine Catalyzed by an Iron(II) Imido Complex: Counterion‐Directed Regioselectivity

open access: yesAngewandte Chemie, Volume 138, Issue 24, 8 June 2026.
Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng   +6 more
wiley   +2 more sources

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