Results 11 to 20 of about 501,263 (263)

Desoxyhemigossypol 6-methyl ether [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2013
The title sesquiterpene [systematic name: 6-methoxy-10-methyl-7-(propan-2-yl)-2-oxatricyclo[6.3.1.04,12]dodeca-1(11),4,6,8(12),9-pentaen-5-ol], C16H18O3, was isolated from pathogen-infected stele tissue ofGossypium barbadense. There are two molecules in the asymmetric unit and the dihedral angle between their naphthofuran systems is 86.48 (2)°.
Vyacheslav V. Uzbekov   +4 more
openaire   +3 more sources

CuCl2-catalyzed One-pot Formation of Tetrahydroquinolines from N-Methyl-N-alkylanilines and Vinyl Ethers in the Presence of t-Butylhydroperoxide

open access: yesMolecules, 2006
Tetrahydroquinoline skeletons can be formed by a CuCl2-catalyzed one-potreaction of N-methyl-N-alkylanilines and vinyl ethers in the presence of t-butyl-hydroperoxide.
Yanfeng Jiang   +2 more
doaj   +1 more source

Analysis of the volatile compounds in Fuliji roast chicken during processing and storage based on GC-IMS

open access: yesCurrent Research in Food Science, 2022
To investigate the flavor changes of Fuliji roast chicken during processing and storage, the volatile organic compounds (VOCs) during processing (fresh, fried, stewed and sterilized) and storage (1 month, 2 months and 4 months) were determined by gas ...
Hui Zhou   +7 more
doaj   +1 more source

Alumination of Aryl Methyl Ethers: Switching Between Sp2 and Sp3 C–O Bond Functionalisation with Pd-Catalysis [PDF]

open access: yes, 2021
The reaction of [{(ArNCMe)2CH}Al] (Ar = 2,6-di-iso-propylphenyl, 1) with aryl methyl ethers proceeded with alumination of the sp3 C–O bond by a presumed SN2 pathway. The selectivity of this reaction could be switched by inclusion of a catalyst.
Thomas N, hooper   +5 more
core   +2 more sources

Oxidation of Secondary Methyl Ethers to Ketones [PDF]

open access: yesThe Journal of Organic Chemistry, 2017
We present a mild way of converting secondary methyl ethers into ketones using calcium hypochlorite in aqueous acetonitrile with acetic acid as activator. The reaction is compatible with various oxygen- and nitrogen-containing functional groups and afforded the corresponding ketones in up to 98% yield.
Gilissen, P.J.   +2 more
openaire   +4 more sources

Radical and Ionic Mechanisms in Rearrangements of o-Tolyl Aryl Ethers and Amines Initiated by the Grubbs–Stoltz Reagent, Et3SiH/KOtBu

open access: yesMolecules, 2021
Rearrangements of o-tolyl aryl ethers, amines, and sulfides with the Grubbs–Stoltz reagent (Et3SiH + KOtBu) were recently announced, in which the ethers were converted to o-hydroxydiarylmethanes, while the (o-tol)(Ar)NH amines were transformed into ...
Krystian Kolodziejczak   +3 more
doaj   +1 more source

Experimental Study of DI Diesel Engine Operational and Environmental Behavior Using Blends of City Diesel with Glycol Ethers and RME

open access: yesEnergies, 2019
An experimental investigation is performed in a single-cylinder direct-injection (DI) diesel engine using city diesel oil called DI1 and two blends of DI1 with a mixture of glycol ethers.
Theodoros C. Zannis   +3 more
doaj   +1 more source

Isobaric Vapour Liquid Equilibrium at 101.3 kPa for the Binary Mixtures 2-Methyl-2-Butene / Methanol and Isopentane / Methanol

open access: yesChemical Engineering Transactions, 2013
Due to the increased interest for using tertiary ethers as fuel additives (such as TAME – tert-amyl-methyl-ether synthesis), the research intensified to study its thermodynamic aspects.
M. Bernabeu Diaz   +4 more
doaj   +1 more source

Synthesis of emodin methyl ethers

open access: yes, 1977
Procedures are summarized for the conversion of emodin (1) into all possible mono- and di-methyl ethers. The 1-methyl ether (2) is characterized for the first time. The 1- and 8-methyl ethers are differentiated by small differences in the chemical shifts
MJ Crossley, DW Cameron
core   +1 more source

Transition-metal-free formal cross-coupling of aryl methyl sulfoxides and alcohols via nucleophilic activation of C-S bond

open access: yesNature Communications, 2020
Cross-coupling processes without the use of transition metals are challenging to achieve. Here, the authors show a transition-metal-free cross-coupling utilizing aryl(heteroaryl) methyl sulfoxides and alcohols to afford alkyl aryl(heteroaryl) ethers and ...
Guolin Li   +7 more
doaj   +1 more source

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