Results 31 to 40 of about 64,940 (304)

Cyanovinylation of Aldehydes: Organocatalytic Multicomponent Synthesis of Conjugated Cyanomethyl Vinyl Ethers

open access: yesMolecules, 2021
A novel organocatalytic multicomponent cyanovinylation of aldehydes was designed for the synthesis of conjugated cyanomethyl vinyl ethers. The reaction was implemented for the synthesis of a 3-substituted 3-(cyanomethoxy)acrylates, using aldehydes as ...
Samuel Delgado-Hernández   +2 more
doaj   +1 more source

Phototauntomerism of o-nitrobenzyl compounds: o-quinonoid aci-nitro species studied by matrix isolation and DFT calculations [PDF]

open access: yes, 2001
Photolyses of 2-nitrobenzyl methyl ether and 2-nitrotoluene with 254 nm light have been investigated in Ar and N2 matrices at 12 K, and have been found to give o-quinonoid aci-nitro species as the primary photoproducts, along with other products.
Dunkin, Ian R.   +3 more
core   +1 more source

Occurrence and Distribution of the Flavone Tricetin and its Methyl Derivatives as Free Aglycones

open access: yesNatural Product Communications, 2008
This paper presents a review of the occurrence of tricetin and its methyl ethers, with respect to their occurrence in the free state. In addition to literature data, our tabulated survey also includes a dozen unpublished results.
Eckhard Wollenweber, Marion Dörr
doaj   +1 more source

High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator. [PDF]

open access: yes, 2017
Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated ...
Berben, Louise A   +3 more
core   +1 more source

Targeting TNBC: core–shell polycationic polyurea dendrimers with inherent anticancer activity

open access: yesFEBS Open Bio, EarlyView.
Core–shell polycationic PURE dendrimers were tested in TNBC‐derived tumor models. Both formulations selectively targeted TNBC and effectively reduced tumor volume. PUREG4‐OEI48 suppressed tumor growth without detectable toxicity, whereas PUREG4‐OCEI24, despite showing efficacy, induced hepatic toxicity.
Adriana Cruz   +9 more
wiley   +1 more source

Selective Electrochemical Conversion of Biomass-derived Valeric Acid to Ethers/Esters

open access: yesInternational Journal of Electrochemical Science, 2018
To quantitatively convert biomass into value-added chemicals or biofuels is still a great challenge. Herein, we develop an efficient electrochemical method to convert the biomass-derived valeric acid into ethers (butyl methyl ether and butyraldehyde ...
Yuchen liu   +3 more
doaj   +1 more source

NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

open access: yesAdvanced Functional Materials, EarlyView.
This study presents novel anti‐counterfeiting tags with multilevel security features that utilize additional disguise features. They combine luminescent nanosized Ln‐MOFs with conductive polymers to multifunctional mixed‐matrix membranes and powder composites. The materials exhibit visible/NIR emission and matrix‐based conductivity even as black bodies.
Moritz Maxeiner   +9 more
wiley   +1 more source

New [4 + 2] Cycloadditions of in situ Generated Indolyl Enol Ethers and Their Anions with Dimethyl Acetylenedicarboxylate: A One-Pot Access to 4-Alkoxy-Substituted Carbazoles

open access: yesCHIMIA, 1992
The 3-indolyl(methyl)methoxycarbenium tetrafluoroborates 1a?d were deprotonated with NaH to furnish in situ the highly reactive 3-indolyl enol ethers 2a or their corresponding 3-indolyl enol ether anions 2b.
Ulf Pindur, Martina Rogge
doaj   +2 more sources

Smart, Bio‐Inspired Polymers and Bio‐Based Molecules Modified by Zwitterionic Motifs to Design Next‐Generation Materials for Medical Applications

open access: yesAdvanced Functional Materials, EarlyView.
Bio‐based and (semi‐)synthetic zwitterion‐modified novel materials and fully synthetic next‐generation alternatives show the importance of material design for different biomedical applications. The zwitterionic character affects the physiochemical behavior of the material and deepens the understanding of chemical interaction mechanisms within the ...
Theresa M. Lutz   +3 more
wiley   +1 more source

Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides [PDF]

open access: yes, 2019
A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions.
Cavedon, Cristian   +3 more
core   +1 more source

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