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Reductive radical chain initiation through the thermal generation of carbon dioxide radical anion. [PDF]

open access: yesNat Synth
Lim ERX   +7 more
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New methyl formate synthesis method: Coal to methyl formate

Journal of Energy Chemistry, 2018
Methyl formate is one of the most important intermediates in C1 chemistry, which has been employed in a wide range of industrial applications. Current synthesis methods for methyl formate mainly include esterification of methanol and formic acid, liquid-phase methanol carbonylation, oxidative dehydrogenation of methanol, one-step syngas synthesis, and ...
Lingyun Rong   +3 more
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Methylation of phenol by methyl formate

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1989
In the presence of ZnCl2 and ZrO2, methyl formate methylates phenol to anisole with a high degree of selectivity.
V. A. Nasadyuk   +3 more
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Vapor−Liquid Equilibrium for Methoxymethane + Methyl Formate, Methoxymethane + Hexane, and Methyl Formate + Methanol

Journal of Chemical & Engineering Data, 2011
Isothermal vapor−liquid equilibrium (VLE) for three binary systems was measured with a static total pressure method. The methoxymethane + methyl formate equilibrium was measured at 308 K, methoxymethane + hexane at 308 K and 335 K, and methyl formate + methanol at 359 K. The measured data were reduced to phase equilibrium data with the Barker's method.
Sundberg, Aarne T.   +4 more
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Photolysis of methyl formate

Transactions of the Faraday Society, 1967
The vapour-phase photolysis of methyl formate has been studied in the temperature range 30–103°C. Methoxyl, methyl and formyl radicals are generated in the photolysis and their reactions have been studied. In this temperature region, radical-radical reactions have been shown to be more important than reactions involving hydrogen atom absotraction from ...
M. J. Yee Quee, J. C. J. Thynne
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Hydrogen Abstraction from Methyl Formate by Methyl Radicals

Canadian Journal of Chemistry, 1971
The reactions of CH3 radicals with methyl formate and CD3 radicals with methyl formate and methyl formate-d have been studied. The CH3 and CD3 radicals were produced by the photolysis of acetone and acetone-d. The Arrhenius parameters (log A, A in 1 mol−1 s−1; E, in kcal mol−1) for hydrogen abstraction are as follows[Formula: see text]
T. R. Donovan, W. Dorko, A. G. Harrison
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An Electron Diffraction Investigation of Methyl Formate, Methyl Acetate and Methyl Chloroformate

Journal of the American Chemical Society, 1950
The structures of simple carboxylic esters have received considerable elucidation from studies of dipole moments. This work is summarized and discussed in the fourth and fifth chapters of Wheland's book, "The Theory of Resonance." 'The conclusion from these studies is that simple aliphatic esters do not have free rotation about the carbonyl carbon ...
O'Gorman, John Michael   +2 more
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