Results 61 to 70 of about 1,867 (215)
This study investigates thermo‐chemical processes during high‐temperature testing of two commercial MgO‐C brick grades, one containing 47.5 wt.% MgO‐C recyclate. Using ETV, DTA/TG‐MS, XRD, and SEM/EDS/EBSD, mechanisms such as carbothermal reduction of magnesia, impurity incorporation into the secondary MgO surface layer, and calcium‐rich phase ...
Alexander Schramm +6 more
wiley +1 more source
BROAD-BAND EMISSION OF Cr3+ IN MgAl2O4 SPINEL
The double luminescence behaviour of Cr (III) in synthetic MgAl2O4 spinel was observed. The nature of such a behaviour is investigated by means the time-resolved luminescence studies at different excitation wavelengths.
P. DERE +2 more
core +1 more source
A carbon‐free, as‐sintered MgO–steel cermet anode, fabricated via cold isostatic pressing using MgO–C refractory recyclate, was evaluated under laboratory‐scale K‐cryolite electrolysis at 800°C. Operation at this reduced temperature, combined with the electrolyte's limited electrical conductivity, led to an increase in cell voltage.
Farhan Hossain +7 more
wiley +1 more source
Water incorporation in synthetic and natural MgAl2O4 spinel [PDF]
The solubility and incorporation mechanisms of water in synthetic and natural MgAl2O4 spinel have been investigated in a series of high-pressure/temperature annealing experiments.
BROMILEY G. D +7 more
core +1 more source
Refractories containing magnesium aluminate spinel (MgAl2O4) are materials for emerging technology in several applications like cement and steelmaking processes.
D. Gutiérrez-Campos +2 more
doaj +1 more source
Interaction of Ladle Slag With Varying SiO2 Content and Recyclate‐Based MgO–C Refractories
Ladle slags (CaO/Al2O3 = 1) with 1–20 wt% SiO2 were investigated in contact with industrial MgO–C refractories fabricated from fresh magnesia and 50 wt% recyclate. The sessile drop method at 1600°C reveals intensive gas formation, delayed slag infiltration in recyclate‐based samples, and, under high‐SiO2 slag, formation of a dense MgAl2O4‐rich ...
Anton Yehorov +6 more
wiley +1 more source
Collagen hydrolysate is evaluated as a sustainable binder for MgO‐C refractories. Its thermally induced cross‐linking and gas release lead to expansion and cracking in large bricks, but tailored batches with lignin, recyclates, or fine graphite improve the gas release while thermal treatment and stability.
Till M. J. Stadtmüller +8 more
wiley +1 more source
This study develops sustainable MgO–C refractories using recycled materials and eco‐friendly fructose–tannin binders. The enhanced performance of citric acid as a cross‐linker and functional additives on mechanical and thermomechanical properties was examined. Characterization included strength tests, immersion trials, and microstructural and inclusion
Dinesh K. Gunasekar +7 more
wiley +1 more source
Highest transparency of MgAl2O4 spinel ceramics prepared by hot pressing with 4.2 wt-% LiF
S.2259-2263Reaction sintering of MgO and Al2O3 with addition of LiF as sintering additive was used to prepare MgAl2O4 spinel ceramic by hot pressing. The process parameter (temperature, pressure, dwell time), the stoichiometric ratio of MgO to Al2O3 and ...
Wätzig, Katja, Hutzler, Thomas
core +1 more source
Cermets (60 vol.% AISI 316L stainless steel, 40 vol.% recycled MgO), intended for use in aluminum electrolysis, were pre‐oxidized in three furnaces with different heating technologies and subjected to a cryolite corrosion test. The different atmospheres influenced the formation of oxide layers, which in turn affected corrosion resistance and ...
Patricia Kaiser +4 more
wiley +1 more source

