Results 171 to 180 of about 502,511 (394)

Probing Metal Tip‐Induced Bond Weakening of a Reactive Alkyne Center Aligned via a Rigid Triphenylmethane‐Based Tripod on Au(111) by TERS and DFT

open access: yesJournal of Raman Spectroscopy, EarlyView.
We investigate tip‐induced bond weakening of a single alkyne center immobilized and aligned upright on Au(111) using a rigid triphenylmethane‐based tripod. By varying the tip–molecule distance, we observe shifts in the ≡C–H and –C≡C– vibrational bands via ultrahigh vacuum low‐temperature tip‐enhanced Raman scattering (TERS).
Gang Li   +12 more
wiley   +1 more source

Identification of Natural and Artificial Modifications in DNA at the Nanometer Level

open access: yesJournal of Raman Spectroscopy, EarlyView.
Short single‐ and double‐stranded DNA sequences with natural and artificial markers are examined at ambient conditions using TERS to identify and localize the labelled nucleobases. The differences between single‐ and double‐stranded DNA should provide clear experimental evidence of the extreme surface sensitivity of TERS.
Tanja Deckert‐Gaudig   +4 more
wiley   +1 more source

Bioanalytical TERS and Advanced Data Processing Methods

open access: yesJournal of Raman Spectroscopy, EarlyView.
Tip‐enhanced Raman spectroscopy delivers label‐free, subnanometer vibrational imaging of biological systems. Recent advances in instrumentation, data analysis, and ambient/liquid operation enable surface‐selective mapping of molecular heterogeneity in proteins, nucleic acids, membranes, and viruses, positioning TERS as a powerful platform for nanoscale
Sarika Joshi   +6 more
wiley   +1 more source

Increasing meniscal repair rates during ACL reconstruction did not increase reoperation risk: An analysis of surgical trends from 2015 to 2023

open access: yesKnee Surgery, Sports Traumatology, Arthroscopy, EarlyView.
Abstract Purpose To evaluate surgical trends over time in meniscal procedures during anterior cruciate ligament reconstruction (ACLR) and compare meniscal reoperation rates and subjective outcomes between 2015–2019 and 2020–2023. Methods This study included 2748 knees undergoing primary ACLR with concomitant meniscal procedures at Capio Artro Clinic ...
Carolina Kekki   +3 more
wiley   +1 more source

Synthesis of Telechelic‐Type Polypeptides Functionalized with Aromatic Units and the Characterization of Their Structures and Thermal Properties

open access: yesMacromolecular Rapid Communications, EarlyView.
Polypeptide chains were extended from both ends of aromatic diamines by chemoenzymatic polymerization, resulting in the synthesis of telechelic polyglycines (TPG) and polyalanines (TPA). These telechelic polymers assembled into branched nanofibrils through π‐π stacking of aromatic rings, with the polymer backbones bent at the aromatic unit.
Yusuke Ueno   +3 more
wiley   +1 more source

Antimicrobial Cyclic Peptidomimetics

open access: yesMacromolecular Rapid Communications, EarlyView.
Singular macromolecular cationic, amphipathic cyclic peptidomimetics with poly(2‐oxazoline)s‐esque backbone structure that undergo self‐assembly in water to form uniform nanoparticles were developed. The cyclic peptidomimetics, which act on bacterial cell membranes, exhibit hydrophobic‐dependent antimicrobial activity and toxicity.
Hao Luo, Edgar H. H. Wong
wiley   +1 more source

Quantitative Analysis of Locus Coeruleus Neurons and Thalamic Noradrenergic Axons in a Progressive 1‐Methyl‐4‐phenyl‐1,2,3,6‐tetrahydropyridine Monkey Model of Parkinson's Disease

open access: yesMovement Disorders, EarlyView.
Abstract Background Parkinson's disease is mainly characterized by dopaminergic neurodegeneration in the substantia nigra pars compacta (SNc) and α‐synuclein accumulation. The locus coeruleus (LC) is also affected in Parkinson's disease and linked to some nonmotor symptoms, but the extent and timing of its degeneration remain unclear.
Megan Carrillo   +6 more
wiley   +1 more source

Matching for the MICA-129 polymorphism is beneficial in unrelated hematopoietic stem cell transplantation [PDF]

open access: bronze, 2016
Daniel Fuerst   +24 more
openalex   +1 more source

Macroscale Gradient‐Informed Neural Oscillation Topography in Parkinson's Disease

open access: yesMovement Disorders, EarlyView.
Abstract Background Parkinson's disease (PD) is characterized by large‐scale disruptions in beta and gamma oscillations. Although subcortical beta power is an established biomarker for current adaptive deep brain stimulation (aDBS), it may not fully capture the global pathophysiological burden and the macroscale hierarchical reorganization of the ...
Hao Ding   +8 more
wiley   +1 more source

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