Results 211 to 220 of about 114,935 (289)

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

open access: yesAngewandte Chemie, EarlyView.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis   +2 more
wiley   +2 more sources

Organic Photoelectrochemical Cells Beyond Performance: Interface and Catalyst Engineering for Durability

open access: yesAdvanced Energy Materials, EarlyView.
Organic photoelectrochemical cells based on π‐conjugated semiconductors offer a versatile platform for solar fuel generation. This review outlines operating principles, device architectures, and key metrics, and highlights advances in p‐ and n‐type photoelectrodes, interfacial engineering, and catalyst integration.
Jaehyeong Kim   +8 more
wiley   +1 more source

From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts

open access: yesAngewandte Chemie, EarlyView.
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk   +4 more
wiley   +2 more sources

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

open access: yesAdvanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Decoding Carbon Dot Purity by Nuclear Magnetic Resonance

open access: yesAngewandte Chemie, EarlyView.
NMR spectroscopy tracks the removal of molecular and oligomeric impurities in carbon dots, enabling a (semi)quantitative evaluation of their purity through integrated peak analysis. ABSTRACT Carbon dots (CDs) have attracted increasing attention in recent years and have been widely explored in many fields.
Yalei Hu, Alberto Bianco
wiley   +2 more sources

One-Pot Synthesis and Surfactant Removal from MCM-41 Using Microwave Irradiation. [PDF]

open access: yesMolecules
Oliveira MR   +6 more
europepmc   +1 more source

Data‐Driven Review and Machine Learning Prediction of Diamond Vacancy Center Synthesis

open access: yesAdvanced Intelligent Systems, EarlyView.
A machine learning framework is applied to photoluminescence spectra to extract linewidths and uncover how NV, SiV, GeV, and SnV centers evolve with growth and processing conditions. Unified normalization and k‐fold validation reveal cross‐method trends and enable rapid prediction of defect size and fabrication parameters, offering a data‐driven route ...
Zhi Jiang   +3 more
wiley   +1 more source

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