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Potential Role of Inorganic Confined Environments in Prebiotic Phosphorylation [PDF]
Life, 2018 A concise outlook on the potential role of confinement in phosphorylation and phosphate condensation pertaining to prebiotic chemistry is presented. Inorganic confinement is a relatively uncharted domain in studies concerning prebiotic chemistry, and ...
Avinash Vicholous Dass +6 more
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Symmetry Breaking of Molecules Triggered by Chiral Inorganic Nanostructures Without Organic Components [PDF]
Advanced ScienceChirality transfer has garnered significant attention due to its potential to revolutionize asymmetric synthesis of enantiopure compounds and to provide fundamental insights into molecular symmetry breaking, which is widely believed to underlie the ...
Tao Yao +3 more
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iScience, 2021 Summary: Ten lanthanacarborane complexes were synthesized to study the rare B−Hδ−∙∙∙Mn+ inverse hydrogen bonds (IHBs). The average bonding energy of B−Hδ−∙∙∙Ln3+ is theoretically determined to be larger than 24 kJ/mol, which is comparable to moderately ...
Peng-Bo Jin +10 more
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A giant spin molecule with ninety-six parallel unpaired electrons
iScience, 2021 Summary: Unpaired electrons which are essential for organic radicals and magnetic materials are hardly to align parallel, especially upon the increasing of spin numbers. Here, we show that the antiferromagnetic interaction in the largest Cr(III)-RE (rare
Lei Qin +5 more
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LAT1 (SLC7A5) catalyzes copper(histidinate) transport switching from antiport to uniport mechanism
iScience, 2023 Summary: LAT1 (SLC7A5) is one of the most studied membrane transporters due to its relevance to physiology in supplying essential amino acids to brain and fetus, and to pathology being linked to nervous or embryo alterations; moreover, LAT1 over ...
Raffaella Scanga +8 more
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iScience, 2021 Summary: This research addresses one of the most compelling issues in the field of photosynthesis, namely, the role of the accessory chlorophyll molecules in primary charge separation.
Michael Gorka +5 more
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Hydrogen evolution catalysis by terminal molybdenum-oxo complexes
iScience, 2021 Summary: Stable complexes with terminal triply bound metal-oxygen bonds are usually not considered as valuable catalysts for the hydrogen evolution reaction (HER).
Pinky Yadav +8 more
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The sustainable production of succinic anhydride from renewable biomass
iScience, 2023 Summary: The selective production of C4 bulk chemicals from biomass is significant to replace the traditional method from petroleum resource. In this work, the succinic anhydride (SAN) is directly prepared from bio-based furanic platform compounds ...
Xiaoqian Gao +3 more
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Molecular mechanics application in inorganic Chemistry [PDF]
Química Nova, 1999 The present paper is a review about basic principles of the molecular mechanics that is the most important tool used in molecular modeling area, and their applications to the calculation of the relative stability and chemical reactivity of organometalic ...
Lilian Weitzel Coelho +4 more
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A Lection in Humbleness: Crystallization of Chiral and Zwitterionic APIs Baclofen and Phenibut
Crystals, 2022 Crystallization and multicomponent crystal formation of active pharmaceutical ingredients Baclofen and Phenibut with dicarboxylic acid co-formers are discussed.
Marco Herbst +3 more
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