Results 11 to 20 of about 2,182 (142)

Kupfer‐katalysierte Monooxygenierung von Phenolen: Evidenz für einen mononuklearen Reaktionsmechanismus [PDF]

open access: yesAngewandte Chemie, Volume 134, Issue 25, June 20, 2022., 2022
Die CuI-Salze [Cu(CH3CN)4]PF und [Cu(oDFB)2]PF mit dem sehr schwach koordinierenden Anion Al(OC(CF3)3)4− (PF), sowie [Cu(NEt3)2]PF mit dem einzigartigen, linearen Bis-Triethylamin-Komplex [Cu(NEt3)2]+ wurden synthetisiert und als Katalysatoren für die ...
Engesser, Tobias A.   +4 more
core   +2 more sources

Polyphenol Oxidase Products Are Priming Agents for LPMO Peroxygenase Activity

open access: yesChemSusChem, Volume 16, Issue 18, September 22, 2023., 2023
Priming versus fueling. It is demonstrated here that the catalytic products of a polyphenol oxidase acting on guaiacol can prime the peroxygenase activity of lytic polysaccharide monooxygenase (LPMO) towards cellulose in H2O2‐driven reactions but do not provide sufficient reducing power to fuel LPMO activity under O2‐driven reactions.
Caio de Oliveira Gorgulho Silva   +5 more
wiley   +1 more source

Dinuclear Copper(I) Complexes Supported by Bis‐Tridentate N‐Donor‐Ligands: Turning‐On Tyrosinase Activity

open access: yesEuropean Journal of Inorganic Chemistry, Volume 2022, Issue 35, December 16, 2022., 2022
Dinuclear copper(I) complexes supported by bis‐tridentate N‐donor ligands with two imine functions mediate the conversion of a monophenol to its corresponding o‐quinone, in contrast to analogous complexes supported by ligands with amine functions. Abstract Four structurally related bis‐tridentate N‐donor ligands with either two secondary amine or two ...
Rebecca Schneider   +4 more
wiley   +1 more source

Bacterial pigments: A colorful palette reservoir for biotechnological applications

open access: yesBiotechnology and Applied Biochemistry, Volume 69, Issue 3, Page 981-1001, June 2022., 2022
Abstract Synthetic derivatives are currently used instead of pigments in many applicative fields, from food to feed, from pharmaceutical to diagnostic, from agronomy to industry. Progress in organic chemistry allowed to obtain rather cheap compounds covering the whole color spectrum. However, several concerns arise from this chemical approach, as it is
Viviana Teresa Orlandi   +4 more
wiley   +1 more source

An organ‐specific transcriptomic atlas of the medicinal plant Bletilla striata: Protein‐coding genes, microRNAs, and regulatory networks

open access: yesThe Plant Genome, Volume 15, Issue 2, June 2022., 2022
Abstract As one of the important species belonging to the Bletilla genus of Orchidaceae, Bletilla striata (Thunb.) Rchb. f., possesses both ornamental and medicinal values. Its dried tubers are used as a traditional Chinese medicine, and several secondary metabolites have been indicated to be the active ingredients.
Xiaoxia Ma   +6 more
wiley   +1 more source

Engineered Bacterial Flavin‐Dependent Monooxygenases for the Regiospecific Hydroxylation of Polycyclic Phenols

open access: yesChemBioChem, Volume 23, Issue 6, March 18, 2022., 2022
The ability to perform regiospecific hydroxylations of sterically challenging monophenols was engineered into a flavin‐dependent monooxygenase. Its variants are valuable tools for production of the corresponding catechols for in vitro or live whole‐cell conversions.
Susann Herrmann   +5 more
wiley   +1 more source

Anthropogenic and natural barriers affect genetic connectivity in an Alpine butterfly

open access: yesMolecular Ecology, Volume 30, Issue 1, Page 114-130, January 2021., 2021
Abstract Dispersal is a key biological process serving several functions including connectivity among populations. Habitat fragmentation caused by natural or anthropogenic structures may hamper dispersal, thereby disrupting genetic connectivity. Investigating factors affecting dispersal and gene flow is important in the current era of anthropogenic ...
Daronja Trense   +5 more
wiley   +1 more source

Functional Substituted Cu(Ii) Schiff Base Complexes, Syntheses, X-Ray And Theoretical Characterizations, And Investigations Of Their Polyphenol Oxidase- And Peroxidase-Like Activities [PDF]

open access: yes, 2021
Some Cu(II) Schiff base complexes were synthesized by a template reaction of salicylaldehyde and amino ethanol or aminoethoxyethanol with Cu(OAc)(2)center dot H2O in methanol solution as the model compounds for mimic enzymatic activities. The synthesized
ARABACI, Gülnur   +5 more
core   +1 more source

습윤조직 접착을 위한 효소 가교 기반의 키토산-페놀 하이드로겔 제작 [PDF]

open access: yes, 2023
학위논문(석사) -- 서울대학교대학원 : 공과대학 화학생물공학부, 2023. 8. Nathaniel Suk-Yeon Hwang.Polyphenols are attractive functional groups since they can attribute versatile properties of hydrogels such as adhesiveness, anti-inflammation, and antibacterial activity.
김수현
core  

티로시나아제 반응을 이용한 수용성 멜라닌 합성 및 효소 코팅 [PDF]

open access: yes, 2022
학위논문(박사) -- 서울대학교대학원 : 공과대학 화학생물공학부, 2022. 8. 김병기.생활성이 있는 나노 물질의 합성은 점점 가속화된 관심을 받고있는 분야이다. 나노 물질 합성은 물리, 화학, 생물적 합성법이 알려져있다. 나노물질은 일반적으로 크기, 물리화학적 성질의 조절에따라 응용 방식이 결정된다. 효소적 합성 방식은 앞선 2가지 방식에 비해서 균질하지 못한 입자의 생산 방식으로 알려져 있어, 반응에 대한 심층적인 분석이 어려웠다.
김현
core  

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