Results 71 to 80 of about 13,617,516 (263)

NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus

Angewandte Chemie, EarlyView.
White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie, Sophia A. Vogler, Gábor Balázs, Francesco Cirigliano, Robert Wolf   +4 more
wiley   +2 more sources

Ruthenium indenylidene "1st generation" olefin metathesis catalysts containing triisopropyl phosphite [PDF]

, 2015
The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the EC (CP-FP 211468-2 EUMET) for funding.The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation ...
Cazin, Catherine, Stefano Guidone, Slawin, Alexandra MZ, Slawin, Alexandra Martha Zoya, Nahra, Fady, Cazin, Catherine S.J., Guidone, Stefano, Catherine S. J. Cazin, Fady Nahra, Alexandra M. Z. Slawin   +9 more
core   +1 more source

Corannulene meets N-heterocyclic carbenes

, 2019
Inspired by the pioneering work of Arduengo et. al and Barth and Lawton, this thesis describes the synthetic strategies attempted and successfully utilised to synthesise novel corannulene-based imidazolium salts preceding N-heterocyclic carbenes ...
Ezzah Mohamed Muzammil
core   +1 more source

The use of the sterically demanding IPr∗ and related ligands in catalysis [PDF]

, 2014
The authors acknowledge the EC for funding through the seventh framework program SYNFLOW, the ERC (Advanced Investigator Award ‘FUNCAT’ to SPN) and the EPSRC.
Manzini, Simone, Izquierdo, F., Izquierdo, Frederic, Nolan, S.P., Manzini, S., Nolan, Steven   +5 more
core   +1 more source

A Facile Route to C2-Substituted Imidazolium Ionic Liquids

Molecules, 2009
A convenient route for the preparation of C2-substituted imidazolium ionic liquids is reported. This method involves the alkylation of N-heterocyclic carbenes, which are readily generated from the C2-unsubstituted imidazolium ionic liquids. It works well
Scott T. Handy, Elliot Ennis
doaj   +1 more source

Copper-NHC complexes in catalysis [PDF]

, 2015
The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.) for funding.Although the chemistry of copper has a long history [1a-d], the relatively recent discovery of N-heterocyclic carbene (NHC) as transition-metal ...
Cazin, Catherine, Nahra, Fady, Cazin, Catherine S.J., Lazreg, Faima   +3 more
core   +1 more source

Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles

Beilstein Journal of Organic Chemistry, 2015
Triaryl-2-pyridylidene effectively facilitates the gold-catalyzed oxidative C–H arylation of heteroarenes with arylsilanes as a unique electron-donating ligand on gold.
Kazuhiro Hata, Hideto Ito, Yasutomo Segawa, Kenichiro Itami   +3 more
doaj   +1 more source

Photochromic diarylethene-containing ionic liquids and N-heterocyclic carbenes

, 2009
The design and synthesis of a series of photochromic diarylethene- containing Arduengo-type N-heterocyclic carbenes (NHCs) of gold(I), silver(I) and palladium(II) and their imidazolium salt precursors are reported.
Zhu, N, Ko, CC, Lee, JKW, Yam, VWW
core   +1 more source

N‐heterocyclic Carbenes as Adhesion Promoters on Aluminum Alloy 6061

Advanced Materials Interfaces
The adhesive industry faces significant challenges in developing effective, simple, safe, and economical surface treatment methods to achieve strong bond strengths and long‐term durability.
Jashanpreet Kaur, Vikram Singh, Alban Morel, Amélie Ruest, Mark D. Aloisio, Cathleen M. Crudden, Janine Mauzeroll   +6 more
doaj   +1 more source

Modulating NHC catalysis with fluorine

Beilstein Journal of Organic Chemistry, 2013
Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was ...
Yannick P. Rey, Ryan Gilmour
doaj   +1 more source