Design and Fabrication of Complex Micro–Nano Structures for Osteogenesis Interfacing in 3D
The graphical abstract demonstrates the 3D Si structure platforms and the cell interactions. (left) Si structures including wine glass‐, obelisk‐, and pillar‐shaped structures are fabricated at wafer scale. (right) Compare to planar Si substrate, the wine glass‐shaped structures demonstrated promising cellular behavior and osteogenesis guidance by ...
Xuanrui Zhou +4 more
wiley +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Synthesis of Benzopyran Atropisomers via Electrophilic Halogenation
We report a halogenation‐based method for the synthesis of axially chiral benzopyrans, tolerating diverse substituents and halogens (Br, Cl, and I). A double bromination gives bisbenzopyrans with two stereogenic axes. Preliminary enantioselective conditions yield benzopyran atropisomer with up to 56% ee.
Alix Bourhis +3 more
wiley +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source
Aminoferrocene‐based prodrugs represent a promising class of redox‐active anticancer agents that can be selectively activated in oxidative cellular environments. However, activation of these systems typically relies on reactive oxygen species (ROS) and is therefore inefficient in intracellular compartments with low ROS levels, such as the cytoplasm. In
Hülya Gizem Özkan +5 more
wiley +1 more source
Synthesis of 2-Naphthols via a Trifluoroacetic Acid-Mediated Epoxy Alcohol Rearrangement. [PDF]
Story JB +4 more
europepmc +1 more source
C-Glycosylation of naphthols using glycosyl donors
Timothy J. Brenstrum, Margaret A Brimble
doaj +1 more source
Hacking a Brønsted photoacid to capture and directly release a Lewis acid: application to CO<sub>2</sub> photorelease. [PDF]
Delibas B +6 more
europepmc +1 more source
Formic Acid Pursues Efficient Hydrodeoxygenation of Naphthols and Phenolic Derivatives to Arenes. [PDF]
Di Erasmo B +4 more
europepmc +1 more source
Sequential oxidative dearomatization/asymmetric homologation: from simple naphthols to chiral benzocycloheptanes. [PDF]
Zeng H +5 more
europepmc +1 more source

