Results 81 to 90 of about 1,728 (205)
Flipping the Card With Enantiodivergent Organocatalysis
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre +3 more
wiley +1 more source
A Catalytic Osmium Redox Couple Collapses Cancer Redox Balance
A stable Os(III)/Os(IV) redox couple is developed to disrupt the tumor cell redox balance by concurrently catalyzing ROS generation and GSH depletion. Osmium‐treated cells exhibit multiple cell death pathways, including apoptosis, ferroptosis, and immunogenic cell death.
Wan‐Qiong Huang +9 more
wiley +1 more source
Accessible and chiroptically tunable helically chiral boron‐dipyrromethene dimer dyes enable the fabrication of solution‐processed isotropic neat thin films that retain sharp visible electronic circular dichroism signatures from solution. This platform establishes a direct molecule‐to‐material relationship and provides a robust foundation for the ...
Carolina Díaz‐Norambuena +11 more
wiley +1 more source
Alpha and beta naphthols, the metabolites of naphthalene, a cataractogenic agent, was tested for it's effect on sheep lens proteases and their inhibitors. It reduced protease activities, not that of inhibitor activities of lens proteins. It also increased the efflux of free amino acid from lenses which was retarded by a high concentration of tissue ...
openaire +1 more source
Mechanochemistry as an Emerging Tool for Organofluorine Chemistry
Fluorinated scaffolds are central across many areas of chemistry, driving the demand for efficient and sustainable synthetic methods. Mechanochemistry has emerged as a powerful alternative to conventional approaches, offering reduced environmental impact, shorter reaction times, and unique reactivity and selectivity.
Marie Caldiero +3 more
wiley +1 more source
Synthesis and application of novel heterocyclic dyes based on 11-amino-13H-acenaphtho[1,2-e]pyridazino[3,2-b]quinazolin-13-one [PDF]
A new fused heterocyclic compound, 11-amino-13H-acenaphtho[1,2-e]pyridazino [3,2-b]quinazolin-13-one was synthesized and used to prepare a novel series of heterocyclic mono azo dyes by coupling with various naphthols.
RANJAN G. PATEL +2 more
doaj
Fermentation significantly altered the dominant bacterial genera from Sphingomonas and Pleomorphomonas (before fermentation) to Weissella and Lactobacillus (after fermentation), while Cladosporium and Fusarium remained the dominant fungal genera. Notably, non‐volatile compounds in de‐pulping coffee beans and volatile compounds of roasted coffee beans ...
Xiaojing Shen +8 more
wiley +1 more source
Parsley (Petroselinum crispum) was harvested at four ontogenetic stages (Pet‐1 to Pet‐4; May–September) under Mediterranean field conditions. Harvest timing significantly affected both agronomic yield and essential oil (EO) composition. Biomass yield peaked at Pet‐4 (10,076 kg da−1); EO content was highest at Pet‐2 (0.70%). GC–MS identified 55 volatile
Ayşe Betül Avci +3 more
wiley +1 more source
ABSTRACT Nanostructured titanium (Ti) facilitates osteoblast differentiation by modulating various signaling pathways and may enhance osseointegration, potentially through its influence on the formation and remodeling of the extracellular matrix (ECM). This study aimed to investigate the impact of osteoblast‐ECM‐functionalized nanostructured Ti surface
Georgia Kors Quiles +7 more
wiley +1 more source
Photochromic carbazole photoinitiators for precision visible‐light photopolymerization
New carbazole–naphthopyran derivatives were employed as visible‐light‐activated photoinitiators, enabling rapid and localized radical photopolymerization to produce well‐defined thin solid objects within minutes. Abstract Two carbazole derivatives, each incorporating a naphthopyran unit and an aromatic ketone, were synthesized and evaluated as ...
Mauro Magalhães +3 more
wiley +1 more source

