Results 61 to 70 of about 5,810 (254)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Multicomponent, Solvent-Free Synthesis of 1-Amidoalkyl-2-naphthols in the Presence of H3+xPMo12-x Vx O40 Heteropolyacids as Recyclable and Green Catalysts

open access: yesE-Journal of Chemistry, 2011
A rapid and efficient one-pot method for the synthesis of 1-amidoalkyl-2-naphthols has been developed in the presence of mixed-addenda vanadium(V)-substituted polyoxomolybdates including: H3+xPMo12-xVxO40 (x=1-3) heteropolyacids (HPAs) as recyclable ...
Fatemeh F. Bamoharram   +3 more
doaj   +1 more source

K2CO3-Promoted oxy-Michael Addition/Cyclization of α,β-Unsaturated Carbonyl Compounds with Naphthols: Synthesis of Naphthopyrans

open access: yesMolecules, 2023
A potassium carbonate promoted tandem oxy-Michael addition/cyclization of α,β-unsaturated carbonyl compounds with naphthol derivatives for the synthesis of 2-substituted naphthopyrans was developed.
Shan-Shan Li   +5 more
doaj   +1 more source

Silica-ZnCl 2 : An Efficient Catalyst for the Synthesis of 4-Methylcoumarins [PDF]

open access: yes, 2013
Silica-ZnCl2 has been found to be an efficient and eco-friendly catalyst for the synthesis of substituted 4-methylcoumarins from ethyl acetoacetate and substituted phenols under “neat” conditions in an oil bath at 80°C.
Bandita Datta, .   +2 more
core   +1 more source

Flipping the Card With Enantiodivergent Organocatalysis

open access: yesChemistry – A European Journal, EarlyView.
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre   +3 more
wiley   +1 more source

Efficient Synthesis of 1-Amidoalkyl-2-Naphthols by One-Pot, Three-Component Reaction under Solvent-Free Conditions

open access: yesJournal of Chemistry, 2013
Two efficient and direct procedures have been developed for the preparation of 1-amidoalkyl-2-naphthols by a one-pot condensation of aldehydes, 2-naphthol, and amides in the presence of trichloroacetic acid or cobalt (II) chloride as catalyst.
Zahed Karimi-Jaberi   +2 more
doaj   +1 more source

Radical scavenging effects of 1-naphthol, 2-naphthol, and their sulfate-conjugates

open access: yesThe Journal of Toxicological Sciences, 2018
1-Naphthol (1-Nap) and 2-naphthol (2-Nap) are phenolic isomers that may be subjected to sulfate conjugation in vivo. Phase-II sulfate conjugation of phenolic compounds is generally thought to result in their inactivation. This study aimed to investigate the antioxidative effects of 1-NapS and 2-NapS, in comparison with their unsulfated counterparts ...
Shintaro, Sugahara   +10 more
openaire   +3 more sources

Matrix‐Free Afterglow Carbon Dots: Synthetic Strategies, Luminescence Mechanisms, and Emerging Applications

open access: yesCarbon Innovation, EarlyView.
This review systematically elucidates the luminescence mechanism, synthesis methods of matrix‐free afterglow carbon dots, and their application progress in information encryption, light‐emitting diodes, sensing, bioimaging, and tumor treatment, and finally, discusses the current challenges and future development directions. ABSTRACT Afterglow materials,
Yupeng Liu   +5 more
wiley   +1 more source

Development of an imidazole salt catalytic system for the preparation of bis(indolyl)methanes and bis(naphthyl)methane.

open access: yesPLoS ONE, 2019
Imidazolium salts are shown to catalyze the rapid room temperature reaction of indoles or naphthol with aldehydes to provide bis(indolyl)methanes or bis(naphthol)methane in excellent yields and the reaction proceeds optimally in dichloromethane with no ...
Xu Wang, Courtney C Aldrich
doaj   +1 more source

The Diaryliodonium(III) Salts Reaction With Free-Radicals Enables One-Pot Double Arylation of Naphthols

open access: yesFrontiers in Chemistry, 2020
The chemoselective reaction of the C- followed by the O-centered naphthyl radicals with the more electron-deficient hypervalent bond of the diaryliodonium(III) salts is described.
Yuvraj Satkar   +5 more
doaj   +1 more source

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