Results 21 to 30 of about 5,721 (226)

Carboxylation of hydroxyarens with metal alkyl carbonates

open access: yesGreen Processing and Synthesis, 2015
The objective of this work was to investigate the possibility of using alkali metal salts of ethylcarbonic acid as a carboxylating reagent in phenol (naphthols) carboxylation and developing a new and simple method for the synthesis of hydroxybenzoic and ...
Suerbaev Khakim A.   +2 more
doaj   +1 more source

1-(Hydroxyiminomethyl)-2-naphthol [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The title compound, C(11)H(9)NO(2), was prepared by a condens-ation reaction of 2-hydr-oxy-1-naphthaldehyde with hydroxyl-ammonium chloride in refluxing ethanol. An intra-molecular O-H⋯N hydrogen bond is observed. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen-bond inter-actions result in a two-dimensional network.
Jianfang Dong   +3 more
openaire   +3 more sources

Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement

open access: yesMolecules, 2015
New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement ...
James Tancock, Thomas Wirth
doaj   +1 more source

THE BETA-NAPHTHOL VS. HYDRO-NAPHTHOL CONTENTION. [PDF]

open access: yesJAMA: The Journal of the American Medical Association, 1889
"Who shall decide when doctors disagree?" says the poet, with as close accordance with a general truth as reason and poetry require. Yet we shall always find, even in the case of the disagreement of doctors, criteria by which rational decision may be reached. In the first place, the opinions of individual doctors, as well as of persons not doctors, are
openaire   +1 more source

Efficient Dihydroxylation of Naphthalene on Photoirradiated Rutile TiO2 Powder in Solution Containing Hydrogen Peroxide [PDF]

open access: yes, 2000
We report on enhanced dihydroxylation of naphthalene on photoirradiated TiO2 particles by addition of H2O2 to the reaction solution. The rate was enhanced by 6–40 times by the addition of H2O2, and the quantum yield reached as high as 76% for rutile TiO2
Jia Jianguang   +2 more
core   +2 more sources

Iridium-Catalyzed, Silyl-Directed, peri -Borylation of C−H Bonds in Fused Polycyclic Arenes and Heteroarenes [PDF]

open access: yes, 2018
peri-Disubstituted naphthalenes exhibit interesting physical properties and unique chemical reactivity, due to the parallel arrangement of the bonds to the two peri-disposed substituents.
Hartwig, John F, Su, Bo
core   +1 more source

Facile Synthesis of 2H-Benzo[h]Chromenes via an Arylamine-Catalyzed Mannich Cyclization Cascade Reaction

open access: yesMolecules, 2021
A simple arylamine-catalyzed Mannich-cyclization cascade reaction was developed for facile synthesis of substituted 2H-benzo[h]chromenes. The notable feature of the process included the efficient generation of ortho-quinone methides (o-QMs) catalyzed by ...
Yueteng Zhang   +5 more
doaj   +1 more source

Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes [PDF]

open access: yes, 2013
BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures.
A McKillop   +45 more
core   +1 more source

Development of Bifunctional Chiral Thioureas and Thiosquaramides in the Synthesis of Betti Bases

open access: yesMolecules, 2023
Bifunctional thioureas and, for the first time, bifunctional thiosquaramides as organocatalysts were used in the asymmetric Betti reaction involving 1-, 2-naphthols and hydroxyquinoline with N-tosylimine and ketimine.
Martyna Malinowska, Anna Zawisza
doaj   +1 more source

Incredible Role of Glycerol in Multicomponent Synthesis of 2,3-Dihydroquinazoline-4(1H)-ones and 1-Amidoalkyl-2-naphthols

open access: yesCroatica Chemica Acta, 2015
An efficient and green synthesis of 1-amidoalkyl-2-naphthols via one-pot three-component condensation of aromatic aldehydes, acetamide and 2-naphthol in the presence of catalytic amounts of glycerosulfonic acid in glycerol as a green solvent was ...
Maryam Hajjami   +2 more
doaj   +1 more source

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