Results 221 to 230 of about 1,092,308 (297)

Unsaturated Coordination Oxygen in Zn─V─O Vacancy Clusters Enables Superb Zinc Storage Capability

open access: yesAdvanced Science, EarlyView.
Zn3(VO4)2 with Zn─V─O vacancy clusters was synthesized and innovatively applied as cathode material in aqueous Zn‐ion batteries. In‐situ XRD, HRTEM and ab initio molecular dynamics simulations unveil the double reaction mechanism of zinc ions. Adsorption of zinc ions on unsaturated coordination O and H+ on O in ‐VO4 contributes to the main capacity. It
Yulong Chi   +8 more
wiley   +1 more source

Robust and Thermally Stable Silicone Aerogels with Hyperconnected Network via Kinetically Optimized Hyperbranched Silane Precursors

open access: yesAdvanced Science, EarlyView.
Reactivity‐Programmed Assembly: A kinetic‐control strategy is reported for constructing hyperconnected silicone aerogels with a robust “thick‐neck” architecture. By exploiting the reactivity disparity of precursors, flexible segments are uniformly embedded within a rigid skeleton.
Aoqing Yan   +9 more
wiley   +1 more source

Electronic‐State Polarization Engineering‐Regulated Fluorinated Covalent Organic Framework Nanocables for Fast Lithium‐Ion Storage

open access: yesAdvanced Science, EarlyView.
Electronic‐state polarization engineering is realized by constructing fluorinated COF nanocables on conductive CNTs scaffolds. The polar C─F units generate localized electric fields and strong ion‐dipole interactions, promoting Li+ adsorption and transport.
Kaifu Xu   +5 more
wiley   +1 more source

Role of Epoxide Functionalization of Amines for Development of Direct Air Capture Sorbents with High Cyclic Working Capacity at Low Desorption Temperatures

open access: yesAdvanced Science, EarlyView.
Appropriate butylene oxide (BO) functionalization of amines (polyethyleneimine (PEI1200 and PEI300) and tris(2‐aminoethyl)amine (TREN)) enables excellent cyclic working capacities (WCcyclic) at low desorption temperatures (40−70°C). Notably, 0.30BO‐PEI300‐SY and 0.54BO‐TREN‐SY show the highest WCcyclic at 45 and 40°C, respectively.
Joo Yeon Han   +10 more
wiley   +1 more source

Helicalization of Covalent Organic Framework Nanofibers with Amplified Spin Polarizability for Boosting Photocatalytic Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
A non‐covalent chirality‐induced strategy via chiral solvents is presented to synthesize helical 2D COF nanofibers with high crystallinity, high chirality, and high spin polarization. The helical structure enhances the concentration of photogenerated charges, suppresses exciton recombination, and extends carrier lifetimes, thereby significantly ...
Qi Zhong   +4 more
wiley   +1 more source

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