Results 141 to 150 of about 51,216 (341)
Low-gravity sloshing in rectangular tanks [PDF]
Low-gravity sloshing in rectangular ...
Dodge, F. T., Garza, L. R.
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Non-Stationary E. M. F. Measurements after Polarization of Solid Galvanic Cells. The Stability of NbO [PDF]
, 1968 G Barbi
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On the Nature of Improper Hydrogen Bonding in RCH2F and RCHF2 Motifs
Angewandte Chemie, Volume 138, Issue 2, 9 January 2026.The nature of ‘improper’ hydrogen bonds is explored in FnC─H⋯X systems, such as RCF2H interaction with chloride and water. It is noted that increased fluorination decreases the positive charge density on H but increases it on C, thus these interactions are dominated by electrostatic attraction to C over H.
Bruno A. Piscelli +3 more
wiley +2 more sources
Aggregate, Volume 7, Issue 2, February 2026.The integration of metal nanoclusters (MNCs) with reticular frameworks (RFs) has recently emerged as a powerful strategy to create composite materials with enhanced and synergistic functionalities. This review provides an overview of the synthetic strategies developed for constructing MNCs/RFs composites and their recent advances in biomedical ...
Wenfeng Liu +3 more
wiley +1 more source
Myths and Truths About Electrophilic Aromatic Substitution: The Particular Case of Fluorobenzene
Journal of Physical Organic Chemistry, Volume 39, Issue 2, February 2026.Nitration σ‐complex formation is exothermic, and halogens—particularly fluorine—enhance para reactivity, challenging traditional descriptions of halogens as purely deactivating in EAS. ABSTRACT Electrophilic aromatic substitution (EAS) is a fundamental reaction introduced early in organic chemistry courses, highlighting the influence of substituents on
Francisco A. Martins +1 more
wiley +1 more source
Understanding β-Hydride Eliminations from Heteroatom Functional Groups [PDF]
, 2011 Using density functional theory, we investigated detailed aspects of the quintessential organometallic process, β-hydride elimination (BHE). In general, we find that most BHE processes from alkyl functional group β-atoms are facile, while BHE processes ...
Goddard, William A. III +1 more
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Direct C─H Lactonization of Carboxylic Acids Enabled by LMCT Photoactivation
Angewandte Chemie, Volume 138, Issue 1, 2 January 2026.We report a photochemical method for oxidative γ‐C─H lactonization of simple carboxylic acid substrates upon LMCT photoactivation. Intriguingly, these conditions suppress the rapid decarboxylation characteristic of oxidized carboxylates, suggesting the intermediacy of metal‐stabilized acyloxy radical instead of the dissociative process typically ...
Kathryn M. Weber +6 more
wiley +2 more sources