Results 111 to 120 of about 226,015 (271)

Speciation, Structural Refinement, and Distribution of Ti Sites in Titanium Silicalite‐1 From 47/49Ti NMR Crystallography at 28.2 Tesla

open access: yesAngewandte Chemie, EarlyView.
Titanium silicalite‐1 (TS‐1), used in industrial selective oxidation processes, depends on specific, yet still unresolved Ti sites, dispersed within the framework of an MFI‐zeolite. Applying high field (28.2 T) 47/49Ti NMR and 17O NMR spectroscopy for an array of TS‐1 catalysts enables the development of an NMR crystallography protocol and the ...
Christoph J. Kaul   +14 more
wiley   +2 more sources

Strain-induced martensitic transformations in tailored microstructures by L-PBF: In situ characterization via advanced neutron imaging

open access: yesJournal of Materials Research and Technology
The possibility of controlling the microstructure in laser powder bed fusion (L-PBF) by locally changing the processing parameters, opens the possibility of building complex structures with tailored microstructures, leading to the development of smart ...
F. Malamud   +6 more
doaj   +1 more source

Dynamic Covalent Networks of Molecular Clusters for Hard and Impact‐Resistant Glass with Feasible Processability

open access: yesAdvanced Science, EarlyView.
Molecular granular material glass is fabricated by crosslinking sub‐nm POSS clusters with dynamic borate ester bonding while the materials combine high transparency, modulus, and hardness with superior impact resistance and (re)processability, offering a promising strategy for creating robust yet highly processable organic glasses.
Haiyan Xiao   +4 more
wiley   +1 more source

Harnessing Phase Separation for the Development of High‐Performance Hydrogels

open access: yesAdvanced Science, EarlyView.
ABSTRACT Hydrogels are indispensable for the development of next‐generation bioelectronics, soft robotics, and biomedical devices, where their mechanical properties determine performance and reliability. Among strategies to enhance hydrogel mechanics, phase separation enables controlled heterogeneity resulting in gel networks that are reinforced by ...
Yue Shao   +3 more
wiley   +1 more source

Anomalous X-ray diffraction studies of ion transport in K+ channels

open access: yesNature Communications, 2018
The number of K+ occupied binding sites in the selectivity filter of potassium ion channels is still under debate. Here, the authors collect diffraction data on the K+ selective NaK channel NaK2K at a wavelength of 3.35 Å, close to the K absorption edge,
Patricia S. Langan   +7 more
doaj   +1 more source

Pressure‐Induced Structural and Magnetic Evolution in Layered Antiferromagnet YbMn2Sb2

open access: yesAdvanced Electronic Materials, EarlyView.
Pressure tunes the delicate balance between structure, magnetism, and electronic states in quantum materials. In YbMn2Sb2, high‐pressure X‐ray and neutron diffraction reveal a trigonal‐to‐monoclinic transition near 3.5 GPa, accompanied by unconventional magnetic ordering.
Mingyu Xu   +9 more
wiley   +1 more source

Synergetic Lattice and Surface Engineering: Stable High‐Voltage Cycle Performance in P3‐Type Layered Manganese Oxide

open access: yesAdvanced Energy Materials, EarlyView.
A dual lattice‐surface strategy employing NaTi2(PO4)3 is adopted to enhance the performance of P3‐type Na0.67[Zn0.3Mn0.7]O2, whereby Ti stabilizes the bulk lattice and surface P species mitigate degradation, collectively improving high‐voltage cycling stability, Na+ diffusion, and oxygen redox reversibility through synergistic structural and ...
Natalia Voronina   +13 more
wiley   +1 more source

Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun   +6 more
wiley   +1 more source

Investigation of the Lithium Extraction Mechanism from LiNi0.6Mn0.2Co0.2O2 by Using Operando Neutron Diffraction in an All‐Solid‐State Battery

open access: yesAdvanced Energy Materials, EarlyView.
All‐solid‐state batteries (ASSB) are promising for high‐energy applications. Using a newly designed electrochemical cell, this study demonstrates reversible Li+ insertion/extraction in a thick ASSB and enables operando neutron diffraction. The results reveal structural evolution and H1‐H2 phase coexistence in LiNi0.6Mn0.2Co0.2O2 (NMC622), while ...
Sreelakshmi Anil Kumar   +7 more
wiley   +1 more source

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