Results 61 to 70 of about 9,887 (194)

Supramolecularly Directed Confined Crystallization of Lamellar Carbon Nitride for Efficient Photocatalytic Hydrogen Generation

open access: yesAdvanced Energy Materials, EarlyView.
ABSTRACT Sustainable hydrogen generation through water splitting is key to realizing a future hydrogen economy. In this study, we achieved molecular‐level control over self‐assembled supramolecular complexes of cyanuric acid and 3‐amino 1,2,4 triazole (AT) monomers. This was coupled with molten‐salt‐assisted thermal polymerization in a eutectic mixture
Nithinraj Panangattu Dharmarajan   +13 more
wiley   +1 more source

The Growth Behavior of Amorphous Hydrogenated Carbon a-C:H Layers on Industrial Polycarbonates—A Weak Interlayer and a Distinct Dehydrogenation Zone

open access: yesC, 2021
Polycarbonate (PC) is a material that is used in many areas: automotive, aerospace engineering and data storage industries. Its hardness is of particular importance, but some applications are affected by its low wettability or scratch susceptibility ...
Torben Schlebrowski   +5 more
doaj   +1 more source

Internal molecular conformation of organic glasses: A NEXAFS study

open access: yesThe Journal of Chemical Physics, 2021
The origin of the exceptional stability of molecular glasses grown by physical vapor deposition (PVD) is not well understood. Differences in glass density have been correlated with thermodynamic stability for thin films of N,N′-Bis(3-methylphenyl)-N,N′-diphenylbenzidine (TPD) grown by PVD at specific substrate temperatures below the glass transition ...
Amara Zuhaib, Stephen G. Urquhart
openaire   +3 more sources

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

open access: yesChemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez   +3 more
wiley   +1 more source

Adsorption of 5-Fluorouracil on Au(111) and Cu(111) surfaces

open access: yesAIP Advances, 2019
The adsorption of 5-Fluorouracil (5FU) on Au(111) and Cu(111) surfaces as a function of molecular coverage and temperature has been studied, using x-ray photoelectron spectroscopy (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy.
Andrew Cassidy   +5 more
doaj   +1 more source

NEXAFS spectroscopy and site-specific fragmentation of N -methylformamide, N,N -dimethylformamide, and N,N -dimethylacetamide [PDF]

open access: yes, 2016
Near-edge X-ray absorption fine-structure (NEXAFS) spectra measured at the C, N, and O K-edges for three molecules containing the amide moiety, N-methylformamide (HCONHCH3), N,Ndimethylformamide (HCON(CH3)2), and N,N-dimethylacetamide (CH3CON(CH3)2 ...
Alagia, Michele   +7 more
core   +1 more source

Probing the Influence of Sulfur–Aromatic Interactions on the Electronic Structure of Gas‐Phase Peptides

open access: yesChemistry – A European Journal, EarlyView.
Just as fingerprints reveal identity, spectroscopic fingerprints reveal molecular secrets. In this article, we show parts of the unique fingerprint of the sulfur–aromatic interaction. By measuring how this force alters the electronic structure of gas‐phase peptides, we provide a fundamental understanding of interactions that give insights into the ...
Laura Pille   +12 more
wiley   +1 more source

Photolysis of Fluorinated Graphites with Embedded Acetonitrile Using a White-Beam Synchrotron Radiation

open access: yesNanomaterials, 2022
Fluorinated graphitic layers with good mechanical and chemical stability, polar C–F bonds, and tunable bandgap are attractive for a variety of applications.
Galina I. Semushkina   +8 more
doaj   +1 more source

Growth and electronic structure of graphene on semiconducting Ge(110)

open access: yes, 2017
The direct growth of graphene on semiconducting or insulating substrates might help to overcome main drawbacks of metal-based synthesis, like metal-atom contaminations of graphene, transfer issues, etc.
Dedkov, Yuriy   +3 more
core   +1 more source

Electronic and magnetic structure of Fe/Co-doped multiwalled carbon nanotubes using X-ray absorption and magnetic circular dichroism spectroscopy

open access: yesAIP Advances
Multi-walled carbon nanotubes (MWCNTs), synthesized using the microwave plasma-enhanced chemical vapor deposition (MPCVD) technique, have been examined to elucidate their electronic and magnetic structures through near-edge X-ray absorption fine ...
Sanjeev Gautam   +7 more
doaj   +1 more source

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