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Role of Residual Li and Oxygen Vacancies in Ni-rich Cathode Materials
ACS Applied Materials & Interfaces, 2021Residual Li and oxygen vacancies in Ni-rich cathode materials have a great influence on electrochemical performance, yet their role is still poorly understood. Herein, by simply adjusting the oxygen flow during the high-temperature sintering process, some Li2O can be carried into the exhaust gas and the contents of residual Li and oxygen vacancies in ...
Lingjun Li +10 more
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Rare Metals, 2021
Abstract Ni‐rich lithium nickel–cobalt‐manganese oxides (NCM) are considered the most promising cathode materials for lithium‐ion batteries (LIBs); however, relatively poor cycling performance is a bottleneck preventing their widespread use in energy systems.
Kwangeun Jung, Taeeun Yim
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Abstract Ni‐rich lithium nickel–cobalt‐manganese oxides (NCM) are considered the most promising cathode materials for lithium‐ion batteries (LIBs); however, relatively poor cycling performance is a bottleneck preventing their widespread use in energy systems.
Kwangeun Jung, Taeeun Yim
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Sulfonate-immobilized artificial cathode electrolyte interphases layer on Ni-rich cathode
Journal of Power Sources, 2017Abstract Although lithium nickel cobalt manganese layered oxides with a high nickel composition have gained great attention due to increased overall energy density for energy conversion/storage systems, poor interfacial stability is considered a critical bottleneck impeding its widespread adoption.
Bum-Jin Chae, Taeeun Yim
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Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode
Science, 2020Cracking the problem of cracking cathodes Polycrystalline cathode materials that contain a combination of nickel, manganese, and cobalt have been used for advanced lithium batteries. These materials fracture at high voltage, which increases surface area and leads to more side reactions and shorter cycle life.
Yujing Bi +11 more
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Improvement of Electrochemical Properties of Ni-Rich Cathode Material by Polypyrrole Coating
Journal of Nanoscience and Nanotechnology, 2016In this study, we attempted a nanosized coating layer of commercial polypyrrole (PPy) on LiNi0.6Co0.1Mn0.3O2 (HNCM) cathode material to overcome the side reactions with electrolyte and a decrease in the capacity of the inert coating layer. The coating method using commercial PPy is very simple.
Gi-Won, Yoo +3 more
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The Role of Cobalt and Manganese for the Safety of Ni-Rich NMC Cathode
ECS Meeting Abstracts, 2021The intrinsic poor thermal stability of layered LiNi x Co y Mn1–x–y O2 (NCM) cathodes and the exothermic side reactions triggered by the associated oxygen release are the main safety threats for their large-scale implantation.
Xiang LIU +5 more
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A Mini Review on Ni-rich Layered Oxide Cathode Materials
Materials Innovations, 2022The global energy demand and increasing global warming are threats to the planet; therefore, replacing internal combustion engine vehicles to electric vehicles is prerequisite. Rechargeable batteries are key component to operate electric vehicles, among which lithium-ion batteries are governing the industry. After the successful discovery of Goodenough’
Sidra Jamil, Muhammad Fasehullah
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A Comprehensive Solution for Ni-Rich Cathodes by Lithium Silicate Coating
Journal of The Electrochemical Society, 2021Ni-rich materials are among the most promising cathode materials for use in the electric vehicle industry with high energy density, excellent low temperature performance and rate performance. However, with the increase of Ni content, many problems emerge in Ni-rich materials, such as residual alkali and the side reactions at the ...
Xin Deng +8 more
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Microstructures of layered Ni-rich cathodes for lithium-ion batteries
Chemical Society ReviewsThe microstructural degradation, stabilization, and characterization of layered Ni-rich cathodes for Li-ion batteries are comprehensively reviewed in this paper.
Jingyu Lu +7 more
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Surface Gradient Ni‐Rich Cathode for Li‐Ion Batteries
Advanced MaterialsAbstractNickel‐rich layered oxide cathode material LiNixCoyMnzO2 (NCM) has emerged as a promising candidate for next‐generation lithium‐ion batteries (LIBs). These cathode materials possess high theoretical specific capacity, fast electron/ion transfer rate, and high output voltage.
Huan Chen +11 more
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