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Cathode Electrolyte Interphase Formation and Electrolyte Oxidation Mechanism for Ni-Rich Cathode Materials

The Journal of Physical Chemistry C, 2020
Herein, we investigate the formation of a cathode electrolyte interphase (CEI) by electrolyte oxidation on a LiNixM1–xO2 (x > 0.5; M, transition metal) layered oxide (Ni-rich) cathode and compare t...
Ikuma Takahashi   +4 more
openaire   +1 more source

Thiophene-initiated polymeric artificial cathode-electrolyte interface for Ni-rich cathode material

Electrochimica Acta, 2018
Abstract Ni-rich layered oxide (Ni-rich NCM) is a promising advanced cathode material for lithium-ion batteries (LIBs) because of its high specific capacity. However, the high Ni content in the layered structures is associated with poor surface stability, which in turn accelerates the capacity fading of the cell.
Bum-Jin Chae   +6 more
openaire   +1 more source

Co‐Doping Engineered High Performance Ni‐Rich Layered Cathode

Small
AbstractAlthough layered oxides of LiNixCoyMnzO2 (NCM, x + y + z = 1) are promising high energy density cathode materials, they still face significant challenges such as the cracks caused by anisotropic strain and poor structural and thermal stability upon building high‐performance rechargeable lithium‐ion batteries (LIBs) for scale‐up ...
Kaili Li   +8 more
openaire   +2 more sources

Kinetic Control of Anisotropic Grain Growth in Ni‐Rich Layered Cathodes

Angewandte Chemie International Edition
Abstract The particle morphology governed by anisotropic grain growth of Ni‐rich layered oxide cathodes plays a crucial role in electrochemical stability and can be tuned via element doping during the high‐temperature lithiation process.
Shuli Zheng   +9 more
openaire   +2 more sources

Surface Reconstruction Reduces Internal Stress of Ni‐Rich Cathode Particles

Small
AbstractHigh‐voltage Ni‐rich layered cathode materials are undoubtedly a powerful driving force for high‐energy density lithium batteries. However, residual lithium impurities on the surface of Ni‐rich materials can cause more severe side reactions under high‐voltage, leading to rapid decay.
Lijuan Hou   +5 more
openaire   +2 more sources

Revisiting Cationic Doping Impacts in Ni-Rich Cathodes

ACS Applied Energy Materials, 2023
Xueyan Hou   +7 more
openaire   +1 more source

Integrated Oxygen-Constraining Strategy for Ni-Rich Layered Oxide Cathodes

ACS Nano
Surface engineering is sought to stabilize nickel-rich layered oxide cathodes in high-energy-density lithium-ion batteries, which suffer from severe surface oxygen loss and rapid structure degradation, especially during deep delithiation at high voltages or high temperatures.
Miao Chang   +6 more
openaire   +2 more sources

Interphasial engineering for Ni-rich NMC cathode materials

Trends in Chemistry, 2023
Zulipiya Shadike   +4 more
openaire   +1 more source

Understanding Surface Reactivity on Ni-Rich Layered Oxide Cathodes

ECS Meeting Abstracts, 2019
The mass market penetration of electric vehicles demand lithium-ion batteries (LIBs) that deliver higher energy density, longer cycle life and better safety. [1] Layered lithium transition-metal oxides, particularly Ni-rich lithium nickel manganese cobalt oxides (LiNi x Mn y
Guoying Chen, Jian Zhu
openaire   +1 more source

Understanding the Effects of Bi Modification on the Properties of Ni‐Rich Cathodes

Batteries & Supercaps
AbstractWith the skyrocketing market demands for energy storage, lithium ions batteries (LIB) with higher energy density are urgently needed. Cathodes play a critical role in determining the energy density of LIB, and the most popular one is Ni‐rich cathode due to its high capacity.
Zifei Meng   +10 more
openaire   +1 more source

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