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The Journal of Physical Chemistry C, 2020
Herein, we investigate the formation of a cathode electrolyte interphase (CEI) by electrolyte oxidation on a LiNixM1–xO2 (x > 0.5; M, transition metal) layered oxide (Ni-rich) cathode and compare t...
Ikuma Takahashi +4 more
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Herein, we investigate the formation of a cathode electrolyte interphase (CEI) by electrolyte oxidation on a LiNixM1–xO2 (x > 0.5; M, transition metal) layered oxide (Ni-rich) cathode and compare t...
Ikuma Takahashi +4 more
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Thiophene-initiated polymeric artificial cathode-electrolyte interface for Ni-rich cathode material
Electrochimica Acta, 2018Abstract Ni-rich layered oxide (Ni-rich NCM) is a promising advanced cathode material for lithium-ion batteries (LIBs) because of its high specific capacity. However, the high Ni content in the layered structures is associated with poor surface stability, which in turn accelerates the capacity fading of the cell.
Bum-Jin Chae +6 more
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Co‐Doping Engineered High Performance Ni‐Rich Layered Cathode
SmallAbstractAlthough layered oxides of LiNixCoyMnzO2 (NCM, x + y + z = 1) are promising high energy density cathode materials, they still face significant challenges such as the cracks caused by anisotropic strain and poor structural and thermal stability upon building high‐performance rechargeable lithium‐ion batteries (LIBs) for scale‐up ...
Kaili Li +8 more
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Kinetic Control of Anisotropic Grain Growth in Ni‐Rich Layered Cathodes
Angewandte Chemie International EditionAbstract The particle morphology governed by anisotropic grain growth of Ni‐rich layered oxide cathodes plays a crucial role in electrochemical stability and can be tuned via element doping during the high‐temperature lithiation process.
Shuli Zheng +9 more
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Surface Reconstruction Reduces Internal Stress of Ni‐Rich Cathode Particles
SmallAbstractHigh‐voltage Ni‐rich layered cathode materials are undoubtedly a powerful driving force for high‐energy density lithium batteries. However, residual lithium impurities on the surface of Ni‐rich materials can cause more severe side reactions under high‐voltage, leading to rapid decay.
Lijuan Hou +5 more
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Revisiting Cationic Doping Impacts in Ni-Rich Cathodes
ACS Applied Energy Materials, 2023Xueyan Hou +7 more
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Integrated Oxygen-Constraining Strategy for Ni-Rich Layered Oxide Cathodes
ACS NanoSurface engineering is sought to stabilize nickel-rich layered oxide cathodes in high-energy-density lithium-ion batteries, which suffer from severe surface oxygen loss and rapid structure degradation, especially during deep delithiation at high voltages or high temperatures.
Miao Chang +6 more
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Interphasial engineering for Ni-rich NMC cathode materials
Trends in Chemistry, 2023Zulipiya Shadike +4 more
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Understanding Surface Reactivity on Ni-Rich Layered Oxide Cathodes
ECS Meeting Abstracts, 2019The mass market penetration of electric vehicles demand lithium-ion batteries (LIBs) that deliver higher energy density, longer cycle life and better safety. [1] Layered lithium transition-metal oxides, particularly Ni-rich lithium nickel manganese cobalt oxides (LiNi x Mn y
Guoying Chen, Jian Zhu
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Understanding the Effects of Bi Modification on the Properties of Ni‐Rich Cathodes
Batteries & SupercapsAbstractWith the skyrocketing market demands for energy storage, lithium ions batteries (LIB) with higher energy density are urgently needed. Cathodes play a critical role in determining the energy density of LIB, and the most popular one is Ni‐rich cathode due to its high capacity.
Zifei Meng +10 more
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