Results 21 to 30 of about 51,764 (223)
π‐Enlargement in Porphyrin Macrocycles at Interfaces
Angewandte Chemie, EarlyView.On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán +11 more
wiley +2 more sources
Kwartalnik Filmowy, 2016 Artykuł zestawia 4’33’’ (1952) Johna Cage’a i Zen for Film (1964) Nam June Paika – dwa przełomowe utwory amerykańskiej awangardy. Andrzej Pitrus próbuje uchwycić rodzaj dialogu, jaki został nawiązany przez dwóch artystów wprowadzających do swego artystycznego języka elementy aleatoryczne.
openaire +4 more sources
Iterative Synthesis of Pentacene Derivatives with Continuous Boron–Oxygen Bonds
Angewandte Chemie, EarlyView.An iterative synthetic strategy enables the controlled introduction of continuous multiple B–O bonds at the zigzag edge of acenes. A simple two‐step cycle—ipso iodination and Suzuki cross‐coupling/condensation—efficiently constructs BO‐acenes ranging from naphthalene to pentacene.
Seonghwa Jeong +8 more
wiley +2 more sources
Angewandte Chemie, EarlyView.We disclose a novel boron macrocycle derived from the sustainable furan building block. The boraporphyrinoid exhibits a global antiaromatic ring current and dynamic conformational flexibility. Twofold reduction induces a switch to strong global aromaticity, accompanied by stiffening of the porphyrinoid backbone.
Lukas Swoboda +6 more
wiley +2 more sources
Identification of Quantitative Trait Loci and Development of Intermediate Breeding Parent for Rice Sheath Blight Resistance [PDF]
The Plant Pathology JournalThe soil-borne pathogen Rhizoctonia solani is one of the most devastating necrotrophic pathogens worldwide, responsible for causing rice sheath blight (RSB).
Chanjeong Jeon +9 more
doaj +1 more source
Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster
Angewandte Chemie, EarlyView.We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang +7 more
wiley +2 more sources
Angewandte Chemie, EarlyView.A five‐membered digermacycle exhibits an unusual 4π electron delocalization enabled by σ*(Ge–C)–π coupling within a nearly planar framework. Combined experimental and theoretical analyses reveal a continuous cyclic delocalization pathway, highlighting σ*–π interactions as a design principle for aromatic stabilization beyond classical π‐conjugated ...
Daichi Uchida +2 more
wiley +2 more sources
Initial Studies of the Effects of Halogenated Dispersions on the Amount of NICS of Rings for C8H12XNO2 [PDF]
International Journal of New Chemistry, 2017 In this research at the first complex and its halogenated derivatives were optimized. NBO calculations and NMR for the complexes were carried out at the B3LYP/6-31G*quantum chemistry level. In the 1- (4-fluorophenyl) -2, 3-dihydro-1 H-naphto- [1, 2-e] [1,
Neda Niakan
doaj +1 more source
Running Neural Networks on the NIC
CoRR, 2020 In this paper we show that the data plane of commodity programmable (Network Interface Cards) NICs can run neural network inference tasks required by packet monitoring applications, with low overhead. This is particularly important as the data transfer costs to the host system and dedicated machine learning accelerators, e.g., GPUs, can be more ...
Siracusano, G +6 more
openaire +3 more sources
Angewandte Chemie, EarlyView.Two spirobisanthracene‐tetraphenylethene (SBA‐TPE) hybrid compounds are synthesized and their photophysical properties in the solid state reported. Circularly polarized luminescence in aggregates, films and dispersions is evaluated. Circularly polarized luminescence imaging is evaluated over crystals revealing discrimination of different types of ...
José L. Páez +7 more
wiley +2 more sources