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SINTESIS 6-NITRO VERATRALDEHID (3,4-DIMETOKSI-6-NITRO BENZALDEHID) DARI VANILIN DENGAN HNO3 DAN CAMPURAN HNO3-H2SO4 [PDF]

open access: yesMolekul, 2009
The synthesis of 6-nitro veratraldehyde from vanillin was used HNO3 and a mixture of HNO3 and H2SO4. The reaction steps were (I) methylation of vanillin and (2) nitration of the methylation product.
Undri Rastuti, Jumina, Sabirin Matsjeh
doaj  

A π-Extended Donor-Acceptor-Donor Triphenylene Twin linked via a Pyrazine-bridge [PDF]

open access: yes, 2015
Beta-amino triphenylenes can be accessed via palladium catalyzed amination of the corresponding triflate using benzophe-none imine. Transformation of amine 6 to benzoyl amide 18 is also straightforward and its wide mesophase range demon-strates that the ...
Andrew N. Cammidge   +43 more
core   +1 more source

Self‐Cascade Catalytic Reaction–Assisted Apoptosis/Calcicoptosis/Ferroptosis Induction with Microsphere‐Aggregated Hydrogels in Triple‐Negative Breast Cancer Therapy

open access: yesAdvanced Functional Materials, EarlyView.
Hyaluronic acid‐dopamine‐based intra‐crosslinked microsphere including cisplatin (HPC MS) is fabricated by spray‐drying and calcium/iron ions are introduced for interparticle crosslinking. Designed microsphere‐aggregated hydrogel (MAH) system including cisplatin/CaO2/FeSO4 can provide apoptosis/calcicoptosis/ferroptosis‐mediated chemo/cascade ...
ChaeRim Hwang   +6 more
wiley   +1 more source

Synthesis and Properties of NitroHPHAC: The First Example of Substitution Reaction on HPHAC

open access: yesMolecules, 2020
Hexapyrrolohexaazacoronene (HPHAC) is one of the N-containing polycyclic aromatic hydrocarbons in which six pyrroles are fused circularly around a benzene.
Yoshiki Sasaki   +3 more
doaj   +1 more source

Oligomerization and tyrosine nitration enhance the allergenic potential of the birch and grass pollen allergens Bet v 1 and Phl p 5

open access: yesFrontiers in Allergy, 2023
Protein modifications such as oligomerization and tyrosine nitration alter the immune response to allergens and may contribute to the increasing prevalence of allergic diseases.
Janine Fröhlich-Nowoisky   +4 more
doaj   +1 more source

The alkaline transition of cytochrome c revisited: Effects of electrostatic interactions and tyrosine nitration on the reaction dynamics [PDF]

open access: yes, 2019
Here we investigated the effect of electrostatic interactions and of protein tyrosine nitration of mammalian cytochrome c on the dynamics of the so-called alkaline transition, a pH- and redox-triggered conformational change that implies replacement of ...
Castro, Maria Ana   +7 more
core   +1 more source

From Low Symmetry to High Dissymmetry: Chiral Plasmonic Films of Binary and Nanobipyramid Assemblies

open access: yesAdvanced Functional Materials, EarlyView.
This work develops highly dissymmetric chiral plasmonic thin films by helically assembling gold nano bipyramids within a liquid‐crystal template. Engineering of the chiroptical response is achieved by varying particle size and geometry, as well as preparing binary assemblies.
Martyna Wasiluk   +10 more
wiley   +1 more source

Features of Nitration of Aromatic Aldehydes with the Difluoromethoxy Group

open access: yesЖурнал органічної та фармацевтичної хімії, 2023
Nitration of aromatic aldehydes with difluoromethoxy group results in the partial ipso-substitution of the aldehyde group if difluoromethoxy group is located in the para-position to the aldehyde group. The presence of a chlorine atom in the meta-position
Kirill I. Petko   +2 more
doaj   +1 more source

Increased glycation and oxidative damage to apolipoprotein B100 of LDL cholesterol in patients with type 2 diabetes and effect of metformin [PDF]

open access: yes, 2010
OBJECTIVE The aim of this study was to investigate whether apolipoprotein B100 of LDL suffers increased damage by glycation, oxidation, and nitration in patients with type 2 diabetes, including patients receiving metformin therapy.
A. Ceriello   +25 more
core   +3 more sources

Transient Stiffness Patterning in Hydrogels Driven by Dissipative Mechanochemical Coupling

open access: yesAdvanced Functional Materials, EarlyView.
Force‐induced disulfide bond rupture in a polymer‐based hydrogel, coupled with chemical or electrochemical reoxidation, leads to the transient modulation of the hydrogel's stiffness properties. High spatiotemporal control is achieved by this dissipative process, enabling the development of out‐of‐equilibrium stiffness patterns and transient, dose ...
Roberto Baretta   +2 more
wiley   +1 more source

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