Results 171 to 180 of about 116,978 (344)

Fe‐Photocatalyzed Decarboxylative Giese‐Type Reaction of α‐N, O or S Carboxylic Acids: Insight into the Mechanism of the Radical Formation

Advanced Synthesis &Catalysis, EarlyView.
Electron‐deficient alkenes can be functionalized with α‐amino, α‐alkoxy and α‐alkylthio radicals formed by Fe‐photocatalyzed decarboxylation of the corresponding carboxylic acids. The reactions proceed under smooth ligandless conditions with inexpensive base and in the absence of oxidant. A mechanistic computational TD‐DFT study supports the occurrence
Fernando Pérez‐Maseda, María Martín, Jorge Labrador‐Santiago, Inés Corral, Diego J. Cárdenas   +4 more
wiley   +1 more source

Studies on the Hydrogenation of Nitriles. I

, 1953
Shunsuke Murahashi, Akira Nishio
openalex   +2 more sources

THE CONVERSION OF α-KETO ACIDS AND OF α-KETO ACID OXIMES TO NITRILES IN AQUEOUS SOLUTION [PDF]

, 1961
A. Ahmad, Ian D. Spenser
openalex   +1 more source

Thioether Synthesis via the Nickel‐Catalyzed Electrochemical Cross Electrophile Coupling of Aryl/Alkyl Disulfides and Aryl/Alkyl Halides

Advanced Synthesis &Catalysis, EarlyView.
A nickel catalyzed electrochemical cross‐electrophile coupling approach for the base‐free synthesis of (un)symmetric (hetero)aryl and alkyl sulfides from organic halides and disulfides is described. The reaction is broadly applicable and tolerates water and air atmosphere. A formal cross‐electrophile coupling approach enables the base‐free synthesis of
Jona Queder, Gerhard Hilt
wiley   +1 more source

Studies of Organic Catalytic Reactions. III. The Hydration Mechanism of Nitriles to Amides with Nickel Catalysts [PDF]

, 1966
Kenichi Watanabe, Koji Sakai
openalex   +1 more source

Recent Advances in Ene Reactions with Carbon Enophiles

Advanced Synthesis &Catalysis, EarlyView.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

1,3-Dipolar Cycloaddition of Nitrile Imines and Nitrile Oxides to Exocyclic C=N Bonds-An Approach to <i>Spiro</i>-N-Heterocycles. [PDF]

Int J Mol Sci
Petrova JV, Kukushkin ME, Beloglazkina EK.   +2 more
europepmc   +1 more source

Verbindungen der Nitrile mit Chlorüren [PDF]

openalex   +1 more source

Visible‐Light Photocatalyzed Selective Synthesis of 1,2‐ or 1,3‐Dithianes From Thietanes: An Experimental and Theoretical Study

Advanced Synthesis &Catalysis, EarlyView.
Although this article formally presents a regioselective photochemical ring enlargement of thietanes into 1,2‐ or 1,3‐dithianes, time‐dependent density functional theory calculations have revealed that 1,3‐dithianes are in fact formed thought photoinduced hydrogen atom transfers from 1,2‐dithianes initially resulting from the ring enlargement using ...
Gabriel Cormier, Manuel Pedrón, Maria I. Lapuh, Regis Guillot, Ilaria Ciofini, Thomas Boddaert   +5 more
wiley   +1 more source

Reactions of Nitrile Imines with Thiohydantoin Derivatives: Unexpected Chemoselectivity of the 1,3-Dipolar Cycloaddition: Preferential Addition of C=C rather than C=S Bonds. [PDF]

ACS Omega
Filkina ME, Zhukov EA, Tafeenko VA, Semykin AV, Kukushkin ME, Nechaev MS, Beloglazkina EK.   +6 more
europepmc   +1 more source