Results 231 to 240 of about 76,223 (304)

Controlled Growth of Oligophenylene‐Structures on Graphene for Facile Secondary Functionalization

open access: yesAngewandte Chemie International Edition, EarlyView.
By thermal decomposition of different BPO‐based peroxides with different substituents, dendrimeric oligophenylene structures with thicknesses up to 10 nm have been grown on graphene in a controlled manner. These newly introduced structures provide active sites for further functionalization as they have a higher reactivity than the graphene lattice, as ...
Christian E. Halbig   +6 more
wiley   +1 more source

closo‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis

open access: yesAngewandte Chemie International Edition, EarlyView.
A strategy to directly synthesize closo‐carboranyl analogs of medicinal chemically important β‐arylethylamines from alkenes is reported. This reaction is enabled by the first formation of closo‐carboranyl radicals by energy transfer (EnT) catalysis and its unique mechanistic features.
Fritz Paulus   +8 more
wiley   +1 more source

Hydrogen Bonding and Noncovalent Electric Field Effects in the Photoconversion of a Phytochrome. [PDF]

open access: yesJ Phys Chem B
Nguyen AD   +12 more
europepmc   +1 more source

Interfacing B‐DNA and DNA Mimic Foldamers

open access: yesAngewandte Chemie International Edition, Accepted Article.
A linker unit was designed and synthesized that can serve both as a hairpin turn in a DNA duplex and anchor point for an aromatic helical foldamer mimicking the shape and surface properties of B‐DNA. Methods were developed to synthesize natural/non‐natural chimeric molecules combining foldamer and DNA segments. The ability of the linker to position the
Manuel Loos   +10 more
wiley   +1 more source

A Cobotic, Digitally‐Controlled Schlenk‐line Unlocks Access to Elusive Lewis‐base stabilised Copper Bis(Disilylamides)

open access: yesAngewandte Chemie International Edition, Accepted Article.
Silylamides are important ligands in coordination chemistry for their ability to stabilize low‐coordination numbers and provide soluble, and even volatile, metal complexes. Such compounds provide valuable insights into the fundamental bonding and reactivity of their respective metals.
Nicola Bell   +5 more
wiley   +1 more source

Home - About - Disclaimer - Privacy