Results 71 to 80 of about 62,179 (283)
STUDIES IN THE PREPARATION OF NITRILES. II. THE PREPARATION OF ALIPHATIC NITRILES. [PDF]
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Epps, G. D. van, Reid, E. Emmet
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Nitrile imines, nitrile oxides and nitrile ylides are widely used in 1,3-dipolar cycloaddition reactions. They also undergo thermal and photochemical rearrangements to carbodiimides, isocyanates, and ketenimines, respectively.
Marchais, Jérémy +7 more
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Electrolyte Design for Fast‐Charging Lithium‐Based Batteries
A decade of progress in fast‐charging electrolytes for lithium batteries is reviewed. Electrolyte design strategies spanning solvents, salts, additives, and advanced systems, such as localized high‐concentration electrolytes (LHCEs), are summarized. Advanced diagnostic tools for lithium plating and interphase chemistry are discussed, with perspectives ...
Chen Liu, Zehao Cui, Arumugam Manthiram
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Generation, identification, and synthetic applications of nitrile sulfides and nitrile selenides
Nitrile sulfides, X-C≡N→S, are important transient species in organic synthesis and widely used for dipolar cycloaddition reactions. Nitrile selenides have the potential to become important dipolarophiles in preparative chemistry, however, their ...
Krebsz, Melinda, Pasinszki, Tibor
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Rapid thiol‐maleimide addition frequently outpaces mixing, resulting in heterogeneous hydrogels. S‐nitrosothiols act as thiol‐protecting groups, allowing uniform mixing with maleimide‐functionalized polymers before gelation. Sodium thiosulfate or sodium ascorbate then regenerates thiols on demand, triggering controlled thiol‐maleimide crosslinking ...
Julian A. Serna +7 more
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Citation: 'nitriles' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.N04151 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
null Anna, George Wypych
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Chinese cabbage is rich in glucosinolates (GLS) and their breakdown products, mainly isothiocyanates (ITC), which are assumed to be human health-promoting compounds.
Christoph-Martin Geilfus +4 more
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Aqueous ammonium‐ion batteries (AAIBs) face a hydrogen‐bond paradox: the HB network enables fast NH4+ transport but triggers water decomposition. This review dissects this dilemma, evaluates multiple electrolyte engineering strategies, and outlines four future directions for next‐generation AAIB design ABSTRACT Aqueous ammonium‐ion batteries (AAIBs ...
Zi‐Hang Huang +6 more
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Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles
The one-pot hydrozirconation of allenes and nitriles followed by an in situ transmetalation of the allylzirconocene with dimethylzinc or zinc chloride provides functionalized homoallylic amines.
Peter Wipf, Marija D. Manojlovic
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Crystal structures of 2,6-dibromo-4-methylbenzonitrile and 2,6-dibromo-4-methylphenyl isocyanide
In the title crystals, C8H5Br2N, which are isomorphous, the steric bulk of the methyl group causes neighboring molecules to become mutually inclined. This prevents the formation of planar or nearly planar sheets, which were observed in the trichloro and ...
Wayland E. Noland +4 more
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