The orthogonal integration of tetraphenylethylene (TPE) and its derivatives into the frameworks of five conventional macrocyclic hosts has garnered significant attention in the field of macrocyclic chemistry. This minireview systematically categorizes TPE‐embedded macrocyclic hosts into three types: non‐, semi‐, and full‐TPE‐embedded skeleton based on ...
Xueqi Tian +3 more
wiley +1 more source
Nickel-catalyzed domino annulation coupling to construct oxindole analogues: A mechanistic and synthetic investigation. [PDF]
Chen H +5 more
europepmc +1 more source
Applications of N─F─Based Reagents in the Synthesis of Organochalcogen Compounds
Herein, we provide a comprehensive review of recent advances in synthetic strategies to access organochalcogen‐decorated compounds using N─F reagents as efficient oxidants for converting chalcogen–chalcogen bonds into electrophilic chalcogen‐based species.
Thiago Anjos +5 more
wiley +1 more source
The Puzzle of the Regioselectivity and Molecular Mechanism of the (3+2) Cycloaddition Reaction Between E-2-(Trimethylsilyl)-1-Nitroethene and Arylonitrile N-Oxides: Molecular Electron Density Theory (MEDT) Quantumchemical Study. [PDF]
Sadowski M, Dresler E, Jasiński R.
europepmc +1 more source
Studies on the [2+3] cycloaddition reaction of nitrile oxides to abietic acid esters
Mirosław Gucma +3 more
openalex +2 more sources
A novel methodology has been developed for the regio‐, chemo‐, and diastereoselective conversion of a broad scope of allylic alcohols into the corresponding gem‐dimethylcyclopropane derivatives. The cyclopropanation reaction proceeds under mild conditions, mediated through an alkylidene titanocene generated in situ from CpTi(IV)Cl3, Mg and 2,2 ...
José Manuel Botubol‐Ares +4 more
wiley +1 more source
Synthesis of Poly‐Substituted Imidazo[1,2‐a]Pyridines via a Double Annulation Strategy
Herein, we report a novel and efficient synthetic strategy for the construction of poly‐substituted imidazo[1,2‐a]pyridines from the reaction of enaminonitriles with propargylamines via a domino conjugate substitution–nucleophilic addition‐cycloisomerization process.
Myungho Jung +4 more
wiley +1 more source
Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases
A novel catalytic mode of aldoxime dehydratases for the abiotic radical ring‐opening reaction of cyclic ketoximes is reported. Aldoxime dehydratase from Nocardioides simplex was found to efficiently generate iminyl radicals from challenging “non‐activated” cycloketone oximes and to promote radical ring‐opening reactions to produce γ‐ and ε‐sulfinylated
Shunsuke Kato +3 more
wiley +2 more sources
Branched Polyacrylonitrile Enabling Highly Lithium-Ion-Conductive Polymer Plastic Crystal Electrolytes. [PDF]
Liu X +8 more
europepmc +1 more source

