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Functionalized Nitrile Oxides and Their Synthetic Equivalents: Recent Advances in Generation Methods and Synthetic Applications [PDF]

Molecules
Functionalized nitrile oxides have attracted increasing attention because the incorporated functional groups not only influence cycloaddition reactivity but also provide valuable handles for subsequent molecular diversification.
Nagatoshi Nishiwaki
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Haloalkalitolerant Nitrile-Utilizing Rhodococcus Strains Promote the Biodegradation of Nitrile-Butadiene Rubber [PDF]

International Journal of Microbiology
Environmental pollution from polymers is reaching alarming levels. Nitrile-butadiene rubber (NBR), widely used in medical glove manufacturing, contributes significantly to plastic and microplastic pollution.
G. A. Syrovatskaya, A. Yu. Maksimov, O. V. Korotchenkova, Yu. G. Maksimova   +3 more
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B–N/B–H Transborylation: borane-catalysed nitrile hydroboration

Beilstein Journal of Organic Chemistry, 2022
The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger, Alexander C. W. Kwok, Franziska Gilch, Dominic R. Willcox, Alex J. Hendy, Kieran Nicholson, Andrew D. Bage, Thomas Langer, Thomas A. Hunt, Stephen P. Thomas   +9 more
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Antifungal Activity of Glucosinolate-Derived Nitriles and Their Synergistic Activity with Glucosinolate-Derived Isothiocyanates Distinguishes Various Taxa of Brassicaceae Endophytes and Soil Fungi

Plants, 2023
The glucosinolates of Brassicaceae plants are converted into bioactive isothiocyanates and other volatiles during a challenge by pathogens and other biotic stressors.
Zsolt Szűcs, Tamás Plaszkó, Eszter Bódor, Hajnalka Csoma, Lajos Ács-Szabó, Attila Kiss-Szikszai, Gábor Vasas, Sándor Gonda   +7 more
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Room Temperature Reduction of Titanium Tetrachloride-Activated Nitriles to Primary Amines with Ammonia-Borane

Molecules, 2022
The reduction of a variety of aromatic and aliphatic nitriles, activated by a molar equivalent of titanium tetrachloride, has been achieved at room temperature using ammonia borane as a safe reductant. The corresponding methanamines were isolated in good
P. Veeraraghavan Ramachandran, Abdulkhaliq A. Alawaed   +1 more
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A Proterozoic microbial origin of extant cyanide-hydrolyzing enzyme diversity

Frontiers in Microbiology, 2023
In addition to its role as a toxic environmental contaminant, cyanide has been hypothesized to play a key role in prebiotic chemistry and early biogeochemical evolution.
Sarah L. Schwartz, Sarah L. Schwartz, Sarah L. Schwartz, L. Thiberio Rangel, Jack G. Payette, Gregory P. Fournier   +5 more
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Crystal structures of three homologues with increasing ring size: 2-methoxy-4-(thiophen-2-yl)-5,6,7,8-tetrahydroquinoline-3-carbonitrile, 2-methoxy-4-(thiophen-2-yl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile and 2-methoxy-4-(thiophen-2-yl)-5,6,7,8,9,10-hexahydrocycloocta[b]pyridine-3-carbonitrile

Acta Crystallographica Section E: Crystallographic Communications, 2023
The title compounds, C15H14N2OS (1a), C16H16N2OS (1b), and C17H18N2OS (1c), form a homologous series in which the size of the saturated ring increases from six- to eight-membered (with four, five and six methylene groups respectively). For 1b and 1c, the
Ali M. S. Hebishy, Galal H. Elgemeie, Lobna M. Gouda, Peter G. Jones   +3 more
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7-Bromo-1-methyl-2-phenyl-1H-indole-3-carbonitrile

Molbank, 2017
The title compound was prepared by electrophilic aromatic substitution of 7-bromo-1-methyl-2-phenyl-1H-indole with NCTS (N-cyano-N-phenyl-p-toluenesulfonamide).
Rosanna Meine, Max Blech, Jens Lindhof, Conrad Kunick   +3 more
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Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

Acta Crystallographica Section E: Crystallographic Communications, 2017
The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl-5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1)]palladium(II) complex.
Jamal Lasri, Naser Eltaher Eltayeb, Matti Haukka, Bandar A. Babgi   +3 more
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Crystal structure of 2,3,5,6-tetrabromoterephthalonitrile

Acta Crystallographica Section E: Crystallographic Communications, 2019
The title crystal (systematic name: 2,3,5,6-tetrabromobenzene-1,4-dicarbonitrile), C8Br4N2, is the first bromo analog in a study of cyano-halo (C[triple-bond]N...X) non-bonded contacts in crystals of halogenated dicyanobenzenes.
Wayland E. Noland, Andrew K. Schneerer, Emilie J. Raberge, Kenneth J. Tritch   +3 more
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