Results 31 to 40 of about 62,179 (283)

Reactivity of the biphasic trichloroacetonitrile-CH2Cl2/H2O2 system in the epoxidation of soybean oil

open access: yesGrasas y Aceites, 2002
In this work we report on the epoxidation of soybean oil by the trichloroacetonitrile -CH2Cl2/H2O2 byphasic system. The reaction was carried out at room temperature and, most importantly, in non acid conditions which prevent the opening of the oxirane ...
Annelise E. Gerbase   +5 more
doaj   +1 more source

Hepatotoxicity of Two Progoitrin-Derived Nitriles in New Zealand White Rabbits

open access: yesToxins, 2020
Cattle occasionally develop brassica-associated liver disease (BALD) and photosensitisation when grazing turnip or swede (Brassica spp.) forage crops. The liver toxin in these brassica varieties has yet to be discovered.
Mark Grey Collett   +2 more
doaj   +1 more source

Crystal structure of ruthenocenecarbonitrile

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The molecular structure of ruthenocenecarbonitrile, [Ru(η5-C5H4C[triple-bond]N)(η5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple-bond]N substituent.
Frank Strehler   +2 more
doaj   +1 more source

Hyperpolarization of Nitrile Compounds Using Signal Amplification by Reversible Exchange

open access: yesMolecules, 2020
Signal Amplification by Reversible Exchange (SABRE), a hyperpolarization technique, has been harnessed as a powerful tool to achieve useful hyperpolarized materials by polarization transfer from parahydrogen.
Sarah Kim   +6 more
doaj   +1 more source

Synthesis of Nitrile-Bearing Quaternary Centers via an Equilibrium-Driven Transnitrilation and Anion-Relay Strategy [PDF]

open access: yes, 2019
The efficient preparation of nitrile-containing building blocks is of interest due to their utility as synthetic intermediates and their prevalence in pharmaceuticals.
Sebastien, Alazet   +3 more
core   +2 more sources

A Nitrile-Tagged Raman Sensor for the Ratiometric Detection of Thiols in Live Cells [PDF]

open access: yes, 2023
Most Raman sensors are based on Raman tags linked to bulky aromatic molecules that affect the subcellular localization. Therefore, here, we developed a small ratiometric Raman sensor, ThioRas, to effectively detect thiols in live cells.
Syusuke, Egoshi   +10 more
core   +2 more sources

Seasonal Variation of Glucosinolate Hydrolysis Products in Commercial White and Red Cabbages (Brassica oleracea var. capitata)

open access: yesFoods, 2020
Brassica vegetables contain glucosinolates, which are well-known for their potential to form health-promoting isothiocyanates. Among those crucifers, white and red cabbage are commonly consumed vegetables, exhibiting different glucosinolate and ...
Nicole S. Wermter   +2 more
doaj   +1 more source

Nitrile rubber and carboxylated nitrile rubber resistance to soybean biodiesel

open access: yes, 2018
Biodiesel has been considered a suitable substitute for petroleum diesel, but their chemical composition differs greatly. For this reason, biodiesel interacts differently than petroleum diesel with various materials, including rubbers.
Felipe Nunes Linhares (4986803)   +4 more
core   +2 more sources

Determination of Phenethyl Isothiocyanate, Erucin, Iberverin, and Erucin Nitrile Concentrations in Healthy and Pieris rapae-Infected Broccoli Tissues Using Gas Chromatography-Mass Spectrometry

open access: yesChemosensors
Cruciferous vegetables (Brassicaceae family) are a rich source of phytochemicals, in particular glucosinolates (GLS) and their hydrolysis products, isothiocyanates and nitriles.
Irene-Dimitra Mesimeri   +3 more
doaj   +1 more source

Functional Expression and Characterization of a Panel of Cobalt and Iron-Dependent Nitrile Hydratases

open access: yesMolecules, 2020
Nitrile hydratases (NHase) catalyze the hydration of nitriles to the corresponding amides. We report on the heterologous expression of various nitrile hydratases.
Birgit Grill   +7 more
doaj   +1 more source

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