Chemistry – A European Journal, EarlyView.Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide-Organoamides: Scope and Mechanism. [PDF]
Angew Chem Int Ed EnglFeng Z +5 more
europepmc +1 more source
Organic and biomolecular chemistry, 2010 Virginie Algay, I. Singh, F. Heaney
semanticscholar +1 more source
Chemistry – A European Journal, EarlyView.A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti +10 more
wiley +1 more source
Dynamic Mechanical Analysis, Morphology, Physico-Mechanical, and Performance Properties of EPDM/NBR Rubber Blends Containing Chlorosulfonated Polyethylene as a Compatibilizer. [PDF]
Polymers (Basel)Egorov E +9 more
europepmc +1 more source
Dipolar Molecular Motor Candidates with Planar Chirality
Chemistry – A European Journal, EarlyView.Two prototypes of molecular motors with simultaneous implementation of planar chirality and a permanent dipole have been designed and synthesized in 7 steps with overall yields of 2.8 to 5.5%. Abstract Two molecular motor candidates built around ruthenium(II) centers featuring both planar chirality and a permanent dipole have been synthesized in seven ...
Thomas A. Hector +5 more
wiley +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Chemistry – A European Journal, EarlyView.Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Fluorinated Para-Quinone Monoacetal: Versatile Reactivity for Constructing Functionalized Scaffolds. [PDF]
Chem Asian JAzami K, Morita M, Suzuki K, Ohmori K.
europepmc +1 more source
Regio‐ and Diastereoselectivity of 1,3‐dipolar Cycloaddition Reaction Between Sugar‐Derived Nitrile Oxides and trans ‐Ethylcinnamate: DFT and QTAIM Analysis [PDF]
Oumayma Abdessadak +3 more
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Pharmaceuticals Made with Hydrogen: A Sustainable and Efficient Approach Using Flow Synthesis
Chemistry – A European Journal, EarlyView.We demonstrate a sustainable strategy for pharmaceutical manufacturing by combining hydrogen, heterogeneous catalysis, and continuous flow synthesis. The development of novel catalysts and their application in a multi‐step synthesis of donepezil enabled a highly productive process with no intermediate purification.
Shū Kobayashi, Haruro Ishitani
wiley +1 more source