Results 261 to 270 of about 3,048,164 (380)

Harnessing Toluene Solvent as a Reactant: Regioselective Benzyl Radical Addition to Multi‐π 1,5‐Enynes in a Copper‐Catalyzed Cascade to Indenes

open access: yesChemistry – A European Journal, EarlyView.
A copper‐catalyzed three‐component radical cascade of 1,5‐enynes with toluene and benzoic acids enables regioselective benzyl radical addition to multi‐Π systems, efficiently delivering polysubstituted indenes from an abundant solvent feedstock. ABSTRACT C─H activation of toluene generates a benzyl radical that undergoes C─C coupling, converting an ...
Saideh Rajai‐Daryasarei   +7 more
wiley   +1 more source

1,3-Dipolar Cycloaddition of Nitrile Oxides and Nitrilimines to (−)-Β-Сaryophyllene: Stereoselective Synthesis of Polycyclic Derivatives and Their Biological Testing

open access: green
Елена К. Белоглазкина   +12 more
openalex   +1 more source

Late‐Stage Phenylation From [13C6] and [2H5]Benzene: A Versatile Tool for Stable Isotope Labeled MS Standards

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT We explored aryl thianthrenation as a tool for directly incorporating multiple isotopes into molecular scaffolds starting from full isotopically labeled benzene. Stable isotope‐labeled (SIL) molecules are indispensable tools for investigating chemical and biological mechanisms and quantifying metabolites.
Alexandre Labiche   +7 more
wiley   +1 more source

Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis

open access: yesChemistry – A European Journal, EarlyView.
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger   +3 more
wiley   +1 more source

Chemo‐Enzymatic Route for Covalent Cellulose Fiber Dyeing

open access: yesChemistry – A European Journal, EarlyView.
This work presents a proof of concept for a chemo‐enzymatic approach to the covalent dyeing of cotton fibers. Laccase/TEMPO oxidation introduces aldehyde groups, enabling subsequent reductive amination with amino dyes. Excellent color homogeneity and wash fastness were demonstrated using acid red 33, highlighting the robustness of the approach and its ...
Awilda Maccow   +6 more
wiley   +1 more source

Photocatalytic Oxygen Evolution with Prussian Blue Coated ZnO Origami Core‐Shell Nanostructures

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Prussian Blue and its derivative hold significant potential for photocatalytic oxygen evolution. IN this contribution the photocatalytic oxygen evolution reaction (OER) was characterized using a hybrid catalyst consisting of Prussian Blue coated ZnO nanostructures. The resulting heterojunction, which was characterized both structurally and functionally,
Ruby Phul   +9 more
wiley   +1 more source

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