Angewandte Chemie International Edition, EarlyView.A one‐pot synthesis for previously unknown heavy carbynes of Group 9 metals is presented. Furthermore, in a hitherto unknown metathetical exchange reaction, the transition metal plumbylidynes were converted into the respective stannylidynes in reaction with terphenyl stannylene chloride, and the germylidynes were formed from the corresponding ...
Lennart G. Holzapfel +5 more
wiley +1 more source
Ruthenium-catalyzed cycloadditions of 1-haloalkynes with nitrile oxides and organic azides: synthesis of 4-haloisoxazoles and 5-halotriazoles. [PDF]
Chemistry, 2014 Oakdale JS, Sit RK, Fokin VV.
europepmc +1 more source
Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?
Angewandte Chemie International Edition, Accepted Article.The incorporation of heteroatoms into the framework of polycyclic aromatic hydrocarbons (PAHs), in particular of nitrogen to yield polycyclic aromatic nitrogen heterocycles (PANHs), has been proposed for both astronomical and combustion environments, but no suitable precursors and pathways have been found.
Rahel Arns +6 more
wiley +1 more source
Copper-catalyzed synthesis of heterocycles via oxidative ring closure reactions of aromatic nitriles with diaryliodonium salts [PDF]
, 2016 Klára Aradi
openalex +1 more source
Controlled Growth of Oligophenylene‐Structures on Graphene for Facile Secondary Functionalization
Angewandte Chemie International Edition, EarlyView.By thermal decomposition of different BPO‐based peroxides with different substituents, dendrimeric oligophenylene structures with thicknesses up to 10 nm have been grown on graphene in a controlled manner. These newly introduced structures provide active sites for further functionalization as they have a higher reactivity than the graphene lattice, as ...
Christian E. Halbig +6 more
wiley +1 more source
Investigation on thermal oxidative aging of nitrile rubber (NBR) O-rings under compression stress [PDF]
, 2017 X R Liu +4 more
openalex +1 more source
Isoxazolodihydropyridinones: 1,3-dipolar cycloaddition of nitrile oxides onto 2,4-dioxopiperidines. [PDF]
ACS Comb Sci, 2012 Coffman KC +3 more
europepmc +1 more source
Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines [PDF]
, 2018 Choon Heng Low +3 more
openalex +1 more source
An Update: Enzymatic Synthesis for Industrial Applications
Angewandte Chemie International Edition, EarlyView.Biocatalysis has become a sustainable and cost‐competitive alternative to established chemical synthesis, enabling the enzyme‐based production of not only commodity chemicals but (non‐natural) amino acids, (rare) sugars, as well as synthetic nucleotides.
Thomas Bayer +4 more
wiley +1 more source