Results 231 to 240 of about 24,787 (265)

Solvent‐Driven Mechanistic Insights into Cu‐Catalyzed Asymmetric C─H Amidation via Nitrene Transfer

open access: yesChemCatChem, EarlyView.
The impact of solvent and ligand in asymmetric Cu‐catalyzed nitrene transfer into a benzylic C─H bond was investigated to provide insights to improve reaction design. Medium‐throughput experimentation, NMR, and CV studies suggest that the anti‐chelate effect on bis(oxazoline) ligands bound to Cu, as well as product inhibition, play key roles in ...
Jed H. Kim   +5 more
wiley   +1 more source

Diverse Cyclization Pathways Between Nitriles with Active α-Methylene Group and Ambiphilic 2-Pyridylselenyl Reagents Enabled by Reversible Covalent Bonding. [PDF]

open access: yesInt J Mol Sci
Artemjev AA   +14 more
europepmc   +1 more source

Catalysis in Chemical Modification of Proteins

open access: yesChemCatChem, EarlyView.
Catalytic principles of synthetic organic chemistry have been increasingly applied to chemical modification of proteins during the recent years. This review article describes how seven types of catalytic systems —electrocatalysis, photocatalysis, metal catalysis, acid catalysis, organocatalysis, supramolecular catalysis, and heterogeneous catalysis ...
Seiya Ishizawa   +4 more
wiley   +1 more source

Organo‐, Metal‐, and Enzyme‐Mediated Stereoselective Transformations of α‐Angelica Lactone

open access: yesChemCatChem, EarlyView.
α‐Angelica lactone is a readily available small molecule from biomass source, which, coupled with cheapness and versatile reactivity, attracted significant interest for applications in asymmetric synthesis. In this minireview, stereoselective organo‐, metal‐, and enzymatic‐based approaches for the construction of new butenolide‐containing heterocycles,
Amina Moutayakine   +2 more
wiley   +1 more source

[CuI(PPh3)3]‐Mediated Arylation of 1,2,3‐Triazoles

open access: yesChemCatChem, EarlyView.
Arylation reactions are a powerful strategy to selectively prepare highly substituted heterocyles. Herein, the arylation of 1,4‐disubstituted 1,2,3‐triazoles with [CuI(PPh3)3] is reported in the presence of air and moisture. Suitable substrates include triazoles containing a pyridyl group, which are of interest in applications such as ancillary ligands
Steven Lal   +5 more
wiley   +1 more source

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