Did organic compounds in the Tagish Lake meteorite form via catalytic processes in the solar nebula and within parent bodies? [PDF]
Gilmour, I.+3 more
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Solvent‐Driven Mechanistic Insights into Cu‐Catalyzed Asymmetric C─H Amidation via Nitrene Transfer
The impact of solvent and ligand in asymmetric Cu‐catalyzed nitrene transfer into a benzylic C─H bond was investigated to provide insights to improve reaction design. Medium‐throughput experimentation, NMR, and CV studies suggest that the anti‐chelate effect on bis(oxazoline) ligands bound to Cu, as well as product inhibition, play key roles in ...
Jed H. Kim+5 more
wiley +1 more source
Diverse Cyclization Pathways Between Nitriles with Active α-Methylene Group and Ambiphilic 2-Pyridylselenyl Reagents Enabled by Reversible Covalent Bonding. [PDF]
Artemjev AA+14 more
europepmc +1 more source
Catalysis in Chemical Modification of Proteins
Catalytic principles of synthetic organic chemistry have been increasingly applied to chemical modification of proteins during the recent years. This review article describes how seven types of catalytic systems —electrocatalysis, photocatalysis, metal catalysis, acid catalysis, organocatalysis, supramolecular catalysis, and heterogeneous catalysis ...
Seiya Ishizawa+4 more
wiley +1 more source
Fe-Catalyzed Fluoroalkyl(hetero)arylation of Vinyl Azaarenes: Rapid and Modular Synthesis of Unsymmetrical 1,1-Bis(hetero)arylalkanes. [PDF]
Guerrero M+3 more
europepmc +1 more source
Nitrile oxide / Isoxazoline route to novel C-Glycosides and C-Disaccharides [PDF]
Ferguson, William James
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Organo‐, Metal‐, and Enzyme‐Mediated Stereoselective Transformations of α‐Angelica Lactone
α‐Angelica lactone is a readily available small molecule from biomass source, which, coupled with cheapness and versatile reactivity, attracted significant interest for applications in asymmetric synthesis. In this minireview, stereoselective organo‐, metal‐, and enzymatic‐based approaches for the construction of new butenolide‐containing heterocycles,
Amina Moutayakine+2 more
wiley +1 more source
Lattice oxygen insertion mechanism in CeO2-catalyzed reactions in water: nitrile hydration reaction. [PDF]
Endo T+5 more
europepmc +1 more source
[CuI(PPh3)3]‐Mediated Arylation of 1,2,3‐Triazoles
Arylation reactions are a powerful strategy to selectively prepare highly substituted heterocyles. Herein, the arylation of 1,4‐disubstituted 1,2,3‐triazoles with [CuI(PPh3)3] is reported in the presence of air and moisture. Suitable substrates include triazoles containing a pyridyl group, which are of interest in applications such as ancillary ligands
Steven Lal+5 more
wiley +1 more source
Synthetic applications of nitrile oxide / isoxazoline chemistry [PDF]
Boyd, Ewan Campbell
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