Results 241 to 250 of about 2,975,483 (362)

Applications of N─F─Based Reagents in the Synthesis of Organochalcogen Compounds

open access: yesAsian Journal of Organic Chemistry, EarlyView.
Herein, we provide a comprehensive review of recent advances in synthetic strategies to access organochalcogen‐decorated compounds using N─F reagents as efficient oxidants for converting chalcogen–chalcogen bonds into electrophilic chalcogen‐based species.
Thiago Anjos   +5 more
wiley   +1 more source

Thermal Insulation Based on NBR-Elastomerized Phenolic Resin Reinforced with Carbon Fibers: Mechanical and Ablation Properties. [PDF]

open access: yesMaterials (Basel)
Gržetić J   +6 more
europepmc   +1 more source

Highly Stereoselective Gem‐Dimethylcyclopropanation of Allylic Alcohols Promoted by Alkylidene Titanocenes

open access: yesAsian Journal of Organic Chemistry, EarlyView.
A novel methodology has been developed for the regio‐, chemo‐, and diastereoselective conversion of a broad scope of allylic alcohols into the corresponding gem‐dimethylcyclopropane derivatives. The cyclopropanation reaction proceeds under mild conditions, mediated through an alkylidene titanocene generated in situ from CpTi(IV)Cl3, Mg and 2,2 ...
José Manuel Botubol‐Ares   +4 more
wiley   +1 more source

Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases

open access: yesAngewandte Chemie, EarlyView.
A novel catalytic mode of aldoxime dehydratases for the abiotic radical ring‐opening reaction of cyclic ketoximes is reported. Aldoxime dehydratase from Nocardioides simplex was found to efficiently generate iminyl radicals from challenging “non‐activated” cycloketone oximes and to promote radical ring‐opening reactions to produce γ‐ and ε‐sulfinylated
Shunsuke Kato   +3 more
wiley   +2 more sources

Synthesis of Poly‐Substituted Imidazo[1,2‐a]Pyridines via a Double Annulation Strategy

open access: yesAsian Journal of Organic Chemistry, EarlyView.
Herein, we report a novel and efficient synthetic strategy for the construction of poly‐substituted imidazo[1,2‐a]pyridines from the reaction of enaminonitriles with propargylamines via a domino conjugate substitution–nucleophilic addition‐cycloisomerization process.
Myungho Jung   +4 more
wiley   +1 more source

Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide–Organoamides: Scope and Mechanism

open access: yesAngewandte Chemie, EarlyView.
Described here is a LaNTMS mediated silylative conversion of primary amides to nitriles under neat reaction conditions. The reaction is highly efficient and selective under such solventless conditions, where all materials are commercially available, demonstrating the robustness and potential of lanthanide heteroatom catalysis.
Zhiyu Feng   +5 more
wiley   +2 more sources

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