Molecules, 2021 Nitriles comprise a broad group of chemicals that are currently being industrially produced and used in fine chemicals and pharmaceuticals, as well as in bulk applications, polymer chemistry, solvents, etc. Aldoxime dehydratases catalyze the cyanide-free
Pablo Domínguez de María
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Nitrile-assistant eutectic electrolytes for cryogenic operation of lithium ion batteries at fast charges and discharges [PDF]
, 2014 The charge/discharge characteristics of lithium ion batteries at low temperature (LT = -20 ??C) are enhanced by using ethylene carbonate (EC)-based electrolytes with the help of assistant solvents of nitriles. Conventional liquid electrolytes (e.g.
Abu-Lebdeh +28 more
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Triphenylphosphine dibromide: A useful reagent for conversion of aldoximes into nitriles
Arabian Journal of Chemistry, 2015 A simple and convenient method for the synthesis of nitriles by dehydration of aldoximes has been developed using triphenylphosphine dibromide in acetonitrile at room temperature.
Fatemeh Darvish +2 more
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Optimized intermolecular potential for nitriles based on Anisotropic United Atoms model [PDF]
, 2008 An extension of the Anisotropic United Atoms intermolecular potential model is proposed for nitriles. The electrostatic part of the intermolecular potential is calculated using atomic charges obtained by a simple Mulliken population analysis.
A St-Amant +46 more
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Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles
Nature Communications, 2017 Difunctionalization of readily available alkenes is a powerful method to quickly build molecular complexity. Here the authors report a three-component, oxidative carboamination between alkenes, alkyl nitriles and amines, producingγ-amino alkyl nitriles.
Yan-Yun Liu +4 more
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An unprecedented palladium-arsenic catalytic cycle for nitriles hydration
Frontiers in Chemistry, 2023 An unprecedented palladium/arsenic-based catalytic cycle for the hydration of nitriles to the corresponding amides is here described. It occurs in exceptionally mild conditions such as neutral pH and moderate temperature (60°C).
Damiano Cirri +2 more
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Isotopic Anomalies in Primitive Solar System Matter: Spin-state Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds [PDF]
, 2012 Organic material found in meteorites and interplanetary dust particles is enriched in D and 15N. This is consistent with the idea that the functional groups carrying these isotopic anomalies, nitriles and amines, were formed by ion-molecule chemistry in ...
Charnley, S. B. +3 more
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Efficient approach for the computational study of alcohol and nitrile adsorption in H-ZSM-5 [PDF]
, 2012 Since many industrially important processes start with the adsorption of guest molecules inside the pores of an acidic zeolite catalyst, a proper estimate of the adsorption enthalpy is of paramount importance.
Hemelsoet, Karen +4 more
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B–N/B–H Transborylation: borane-catalysed nitrile hydroboration
Beilstein Journal of Organic Chemistry, 2022 The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger +9 more
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Micellar electrokinetic capillary chromatography—Synchronous monitoring of substrate and products in the myrosinase catalysed hydrolysis of glucosinolates [PDF]
, 2006 A micellar electrokinetic capillary chromatography (MECC) method has been developed for monitoring the myrosinase catalysed hydrolysis of 2-hydroxy substituted glucosinolates and the simultaneous formation of the corresponding degradation products ...
Bellostas, Natalia +2 more
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