Molecules, 2009 Microwave assisted CpCo(CO)2 catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied.
Aneta Kadlčíková, Martin Kotora
doaj +1 more source
Soft-SAFT modeling of vapour liquid equilibria of nitriles and their mixtures [PDF]
, 2010 Nitriles are strong polar compounds showing a highly non-ideal behavior, which makes them challenging systems from a modeling point of view; in spite of this, accurate predictions for the vapor-liquid equilibria of these systems are needed, as some of ...
Belkadi, Abdelkrim +4 more
core +2 more sources
Impact of Nitriles on Bacterial Communities
Frontiers in Environmental Science, 2019 Nitriles are organic molecules with –C≡N as functional group and often toxic for living organisms. Detoxification can occur via nitrilases that degrade nitriles directly to carboxylic acids and ammonia, or with nitrile hydratases and amidases that ...
Richard Egelkamp +4 more
doaj +1 more source
Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles
Nature Communications, 2017 Difunctionalization of readily available alkenes is a powerful method to quickly build molecular complexity. Here the authors report a three-component, oxidative carboamination between alkenes, alkyl nitriles and amines, producingγ-amino alkyl nitriles.
Yan-Yun Liu +4 more
doaj +1 more source
Isotopic Anomalies in Primitive Solar System Matter: Spin-state Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds [PDF]
, 2012 Organic material found in meteorites and interplanetary dust particles is enriched in D and 15N. This is consistent with the idea that the functional groups carrying these isotopic anomalies, nitriles and amines, were formed by ion-molecule chemistry in ...
Charnley, S. B. +3 more
core +3 more sources
Chemistry Proceedings, 2022 There exist a number of classical methods for the synthesis of substituted pyrazines. Among this variety of reactions, the synthesis of substituted pyrazines from nitriles does not stand out in either the number of known examples or in product yield ...
Mariya G. Shaibakova +3 more
doaj +1 more source
Micellar electrokinetic capillary chromatography—Synchronous monitoring of substrate and products in the myrosinase catalysed hydrolysis of glucosinolates [PDF]
, 2006 A micellar electrokinetic capillary chromatography (MECC) method has been developed for monitoring the myrosinase catalysed hydrolysis of 2-hydroxy substituted glucosinolates and the simultaneous formation of the corresponding degradation products ...
Bellostas, Natalia +2 more
core +1 more source
Vacuum ultraviolet photoabsorption spectra of nitrile ices for their identification on Pluto [PDF]
, 2016 Icy bodies, such as Pluto, are known to harbor simple and complex molecules. The recent New Horizons flyby of Pluto has revealed a complex surface composed of bright and dark ice surfaces, indicating a rich chemistry based on nitrogen (N2), methane (CH4),
B. N. Raja Sekhar +14 more
core +2 more sources
Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
Nature Communications, 2020 Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range
Yanan Dong +3 more
doaj +1 more source
B–N/B–H Transborylation: borane-catalysed nitrile hydroboration
Beilstein Journal of Organic Chemistry, 2022 The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger +9 more
doaj +1 more source