Results 11 to 20 of about 15,386 (167)

Composés d'addition des halogénures de niobium(V) et de tantale(V): II. Stabilité relative des composés des chlorures avec quelques éthers, sulfures et nitriles

open access: yesCHIMIA, 1971
New NMR methods for the determination of relative stability constants are developed. These methods are used for the study of niobium(V) and tantalum(V) chlorides adducts with series of ethers, sulfides, and nitriles. The relative stabilities of nitriles
A. Merbach, J.-C. Bünzli
doaj   +1 more source

Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles

open access: yesNature Communications, 2022
Exploring benign and green methodologies for the synthesis of functionalized nitriles continues to attract the interest of academic and industrial chemists.
Kangkang Sun   +4 more
doaj   +1 more source

Nitrile Synthesis with Aldoxime Dehydratases: A Biocatalytic Platform with Applications in Asymmetric Synthesis, Bulk Chemicals, and Biorefineries

open access: yesMolecules, 2021
Nitriles comprise a broad group of chemicals that are currently being industrially produced and used in fine chemicals and pharmaceuticals, as well as in bulk applications, polymer chemistry, solvents, etc. Aldoxime dehydratases catalyze the cyanide-free
Pablo Domínguez de María
doaj   +1 more source

Supported Palladium Nanoparticles Catalyzed Intermolecular Carbopalladation of Nitriles and Organoboron Compounds

open access: yesFrontiers in Chemistry, 2022
The first heterogeneous catalyzed example for the direct synthesis of aromatic ketones via intermolecular carbopalladation of aliphatic nitriles and organoboron compounds was developed.
Xin Liu   +5 more
doaj   +1 more source

Impact of Nitriles on Bacterial Communities

open access: yesFrontiers in Environmental Science, 2019
Nitriles are organic molecules with –C≡N as functional group and often toxic for living organisms. Detoxification can occur via nitrilases that degrade nitriles directly to carboxylic acids and ammonia, or with nitrile hydratases and amidases that ...
Richard Egelkamp   +4 more
doaj   +1 more source

Cross-Cyclotrimerization with Two Nitriles as a Synthetic Pathway to Unsymmetrically 3,3’-Disubstituted bis(Tetrahydroisoquinolines)

open access: yesMolecules, 2009
Microwave assisted CpCo(CO)2 catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied.
Aneta Kadlčíková, Martin Kotora
doaj   +1 more source

Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles

open access: yesNature Communications, 2017
Difunctionalization of readily available alkenes is a powerful method to quickly build molecular complexity. Here the authors report a three-component, oxidative carboamination between alkenes, alkyl nitriles and amines, producingγ-amino alkyl nitriles.
Yan-Yun Liu   +4 more
doaj   +1 more source

Multiple Pathways in Cp2TiCl2—Catalyzed Reaction of Tetraalkyl-Substituted Pyrazines with EtAlCl2 and Mg

open access: yesChemistry Proceedings, 2022
There exist a number of classical methods for the synthesis of substituted pyrazines. Among this variety of reactions, the synthesis of substituted pyrazines from nitriles does not stand out in either the number of known examples or in product yield ...
Mariya G. Shaibakova   +3 more
doaj   +1 more source

Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species

open access: yesNature Communications, 2020
Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range
Yanan Dong   +3 more
doaj   +1 more source

B–N/B–H Transborylation: borane-catalysed nitrile hydroboration

open access: yesBeilstein Journal of Organic Chemistry, 2022
The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger   +9 more
doaj   +1 more source

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