Results 11 to 20 of about 15,386 (167)
New NMR methods for the determination of relative stability constants are developed. These methods are used for the study of niobium(V) and tantalum(V) chlorides adducts with series of ethers, sulfides, and nitriles. The relative stabilities of nitriles
A. Merbach, J.-C. Bünzli
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Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles
Exploring benign and green methodologies for the synthesis of functionalized nitriles continues to attract the interest of academic and industrial chemists.
Kangkang Sun +4 more
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Nitriles comprise a broad group of chemicals that are currently being industrially produced and used in fine chemicals and pharmaceuticals, as well as in bulk applications, polymer chemistry, solvents, etc. Aldoxime dehydratases catalyze the cyanide-free
Pablo Domínguez de María
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The first heterogeneous catalyzed example for the direct synthesis of aromatic ketones via intermolecular carbopalladation of aliphatic nitriles and organoboron compounds was developed.
Xin Liu +5 more
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Impact of Nitriles on Bacterial Communities
Nitriles are organic molecules with –C≡N as functional group and often toxic for living organisms. Detoxification can occur via nitrilases that degrade nitriles directly to carboxylic acids and ammonia, or with nitrile hydratases and amidases that ...
Richard Egelkamp +4 more
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Microwave assisted CpCo(CO)2 catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied.
Aneta Kadlčíková, Martin Kotora
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Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles
Difunctionalization of readily available alkenes is a powerful method to quickly build molecular complexity. Here the authors report a three-component, oxidative carboamination between alkenes, alkyl nitriles and amines, producingγ-amino alkyl nitriles.
Yan-Yun Liu +4 more
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There exist a number of classical methods for the synthesis of substituted pyrazines. Among this variety of reactions, the synthesis of substituted pyrazines from nitriles does not stand out in either the number of known examples or in product yield ...
Mariya G. Shaibakova +3 more
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Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range
Yanan Dong +3 more
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B–N/B–H Transborylation: borane-catalysed nitrile hydroboration
The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger +9 more
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