Results 41 to 50 of about 27,368 (206)
Molecules, 2013 We have demonstrated that a cooperative catalytic system comprised of CuCl and Cu(OTf)2 could be used to effectively catalyse the three-, five- and seven-component coupling reactions of aliphatic or aromatic amines, formaldehyde, and trimethylsilyl ...
Takeo Konakahara +4 more
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Triflic Anhydride Promoted Synthesis of Primary Amides and their Conversion into Nitriles
SynOpen, 2018 A facile, two-pot conversion of carboxylic acids into the corresponding nitriles has been developed using triflic anhydride as a promoter and aqueous NH4OH as a source of nitrogen.
Anil Rana +5 more
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B–N/B–H Transborylation: borane-catalysed nitrile hydroboration
Beilstein Journal of Organic Chemistry, 2022 The reduction of nitriles to primary amines is a useful transformation in organic synthesis, however, it often relies upon stoichiometric reagents or transition-metal catalysis.
Filip Meger +9 more
doaj +1 more source
Unsaturated Nitriles: Stereoselective MgO Eliminations
, 2016 α,β-Unsaturated nitriles are readily synthesized by eliminating MgO from β-hydroxynitriles. Deprotonating acyclic, and cyclic, β-hydroxynitriles with excess MeMgCl smoothly generates dianion intermediates that eject MgO with concurrent formation of α,β ...
Fraser F. Fleming (1520524) +1 more
core +1 more source
Nickel-Catalyzed Reductive Cyanation of Aryl Halides and Epoxides with Cyanogen Bromide
MoleculesNitriles are valuable compounds because they have widespread applications in organic chemistry. This report details the nickel-catalyzed reductive cyanation of aryl halides and epoxides with cyanogen bromide for the synthesis of nitriles.
Yu-Juan Wu +3 more
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A DFT Study on the Excited Electronic States of Cyanopolyynes: Benchmarks and Applications
Molecules, 2022 Highly unsaturated chain molecules are interesting due to their potential application as nanowires and occurrence in interstellar space. Here, we focus on predicting the electronic spectra of polyynic nitriles HC2m+1N (m = 0–13) and dinitriles NC2n+2N (n
Marcin Gronowski, Robert Kołos
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Preparation of unsaturated nitriles
, 1983 The yield and the rate of formation of nitriles X-CH=CH-CN and 3- and 4-substituted nitriles X-C6H5CN (X = CH3; OR; SR; COOCH3) were investigated in the reaction of vinyl and aryl bromides with CN(-), under catalysis with Pd0 and macrocyclic polyethers ...
Miroslav Široký, Miloš Procházka
core +1 more source
ON THE PREPARATION OF FUMARIC NITRILE. THE ACTION OF HYDROXYLAMINE ON FUMARIC NITRILE. [PDF]
Journal of the American Chemical Society, 1918 n ...
McMaster, L., Langreck, F. B.
openaire +1 more source
Molecular modeling for physical property prediction [PDF]
, 2006 Multiscale modeling is becoming the standard approach for process study in a broader framework that promotes computer aided integrated product and process design.
Joulia, Xavier, Gerbaud, Vincent
core
Metalated Nitriles: Cation-Controlled Cyclizations
, 2016 Judicious choice of cation allows the selective cyclization of substituted γ-hydroxynitriles to trans- or cis-decalins and trans- or cis-bicyclo[5.4.0]undecanes.
Fraser F. Fleming (1520524) +3 more
core +2 more sources