Results 71 to 80 of about 124,019 (286)

Electrocatalytic Nitrate Reduction to Hydroxylamine: Breaking the Activity‐Selectivity Trade‐Off by Designer Bifunctional Metal‐Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
A bifunctional metal‐organic framework (MOF) catalyst with dual active sites is developed for enabling NH2OH electrosynthesis via NitRR with both high selectivity and activity. ABSTRACT Electrocatalytic nitrate reduction reaction (NitRR) offers a promising route for hydroxylamine (NH2OH) synthesis under ambient conditions.
Yingying Zou   +9 more
wiley   +2 more sources

Molecular Weaving of Mixed‐Addenda Polyoxometalates into MOF Nanochannels as Electron‐Buffering Reservoirs for Enhanced Nitrate‐to‐Ammonia Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Synergistic interaction between P2W17V1 and FeMOF owing to its efficient proton/electron transfer affording high yield and Faradaic efficiency in electrocatalytic nitrate reduction to ammonia. ABSTRACT Electrochemical conversion of nitrate pollutants into value‐added ammonia (e‐NO3RA) offers a sustainable pathway for nitrogen valorization, yet hinges ...
Gang Li   +3 more
wiley   +1 more source

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +2 more sources

Bridging Green Chemistry and Circular Economy: A Pathway to Sustainable Polyester Plastics Through Feedstock, Synthesis, and Waste Upcycling

open access: yesAdvanced Science, EarlyView.
This review summarizes green and low‐carbon strategies throughout the entire life cycle of polyester plastics, including sustainable monomer synthesis, optimization polymerization, efficient recycling, and advanced upcycling technologies. The synergistic implementation of these strategies is expected to significantly promote the development of a ...
Jinzhou Li   +5 more
wiley   +1 more source

Proximity Engineering of Fe‒N4 Twins for Oriented Generation of Singlet Oxygen for Hospital Wastewater Treatment

open access: yesAngewandte Chemie, EarlyView.
Precise modulation of Fe–N4 site distances constructs spin‐regulated Fe–N4 twins, triggering a volcano‐type Fenton‐like activity and promoting oriented singlet oxygen generation. The twin‐site catalyst enables highly selective and efficient hospital wastewater purification with simultaneous pharmaceutical degradation and disinfection under low ...
Xinhao Wang   +10 more
wiley   +2 more sources

Comparison between biochemical responses of the teleost pacu and its hybrid Tambacu (Piaractus mesopotamicus xColossoma macropomum) to short term nitrite exposure

open access: yesBrazilian Journal of Biology
Aquatic environmental factors are very changeable in short periods. Among these factors are pH, temperature, dissolved oxygen, ammonia and ions. Nitrite, as one ion naturally present in aquatic systems, deserves particular consideration as it is highly ...
G. Moraes, I. M. Avilez, T. S. F. Hori
doaj   +1 more source

Ni Single‐Atom Modulation of Ti‐O Covalency Boosts Ammonia Oxidation Electrocatalysis

open access: yesAdvanced Science, EarlyView.
A Ni single‐atom‐induced enhancement of Ti‐O covalency in Ni SAC@TiO2 generates abundant active sites and promotes selective NHx‐NHy mediated N2 evolution while suppressing poisonous NOx formation, achieving nearly doubled AOR activity with excellent durability.
Subhash Chandra Shit   +7 more
wiley   +1 more source

Synergetic Relay Between Atomic Hydrogen and Chlorine Radicals Enables Efficient Nitrate‐to‐Nitrogen Gas Conversion

open access: yesAdvanced Science, EarlyView.
Using photoelectrochemical (PEC) deep denitrification technology, a novel synergistic reduction‐oxidation process enables efficient conversion of nitrate (NO3−) to nitrogen (N2), while suppressing key intermediate ammonium (NH4+) and toxic nitrite (NO2−) accumulation.
Yongjie Wang   +11 more
wiley   +1 more source

Concentration of nitric oxide oxidation products and antioxidant vitamins in chicken fed with supplemental zinc [PDF]

open access: yesEurasian Journal of Veterinary Sciences
The aim o! this study ts to determine o! the effect of supplemental zinc on the concentration of the oxidation products of nilnc oxide and antioxidant vitamins in chicken serum.
Semiha Dede   +3 more
doaj  

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