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Reversible photoswitching between nitrito-N and nitrito-O isomers in trans-[Ru(py)4(NO2)2]
Physical Chemistry Chemical Physics, 2010Nitro-nitrito photoisomerisation is investigated in solid samples and solutions of trans-[Ru(py)(4)(NO(2))(2)]. Using light of wavelength 325 nm 50% of the N-bound Ru-NO(2) ligands can be switched to the O-bound Ru-ONO configuration (nitrito-N to nitrito-O isomerisation) at temperatures below T = 250 K in solids.
Dominik Schaniel +2 more
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Abstract The preparation and characterization of some copper(II)nitrito complexes with 2,2′-dipyridylamine (dipyam) are reported. The X-ray diffraction crystal structures of the [Cu(CH3COO)(dipyam)(ONO-O,O′)] (I) and [Cu(dipyam)(ONO-O,O′)(μ-ONO-O)]2·2CH3CN (II) complexes have been investigated.
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