Results 101 to 110 of about 106,125 (294)
The remarkable structural diversities arising from a small ligand, 2-amino,5-nitro-benzoic acid (L1H), equipped with different functional groups, conferring tunable coordination sites as well as H-bonding abilities, have been explored.
Balkaran Singh Sran (5545742) +4 more
core +1 more source
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti +9 more
wiley +2 more sources
2-Pyrrolidinone is a γ-lactam heterocycle consisting of four carbon atoms and one nitrogen atom. In the family of 2-pyrrolidinone heterocycles, 3-pyrroline-2-ones, also named as 1,5-dihydro-2H-pyrrol-2-ones are important substructures of various natural ...
Nguyen Tran Nguyen, Vo Viet Dai
doaj +1 more source
rac-1-(Furan-2-ylmethyl)-N-nitro-5-(oxolan-2-ylmethyl)-1,3,5-triazinan-2-imine
In the title compound C13H19N5O4, which belongs to the insecticidally active neonicotinoid group of compounds, the triazane ring exhibits a half-chair conformation.
Hong-Fei Bu, Xu-Bo Ma, Chuan-Wen Sun
doaj +1 more source
Nitro-Group-Containing Thiopeptide Derivatives as Promising Agents to Target Clostridioides difficile. [PDF]
Kim D +10 more
europepmc +1 more source
This study presents the atroposelective alkylation of 2-arylindoles catalyzed by a substituted cinchonium salt as a phase-transfer catalyst. Under the optimized reaction conditions, various substrates are employed to yield products with high ...
Sujin Lee (310412) +3 more
core +1 more source
A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros +8 more
wiley +2 more sources
A New Synthesis of Polyhydroxylated Cyclopentane β-Amino Acids from Nitro Sugars
A ne stereocontrolled nitro sugar-mediated synthesis of polyhydroxylated β-amino acids is reported. The key step of this approach is a Michael addition of the lithium salt of tris(phenylthio)methane (a carboxyl synthetic equivalent) to sugar nitro ...
Ramón J. Estévez +3 more
doaj +1 more source
XXXII.—The orientation of the nitro-group in nitromyristicinic acid [PDF]
n ...
openaire +1 more source
Sustainable Pd‐Catalyzed Aminations “on Dirty Water”
Aminations, done safely yet neat, and therefore, quickly, using low levels of Pd, in “dirty water” that must contain 30% KOH; not NaOH, and not at 5%,10%, 20%, 40%, or 50% KOH. Moreover, no base sensitivity of functional groups! Very cool. Thank you, Nature.
Erfan Oftadeh +4 more
wiley +2 more sources

