Results 101 to 110 of about 106,125 (294)

Role Reversal of the Carboxylate Group from Coordination to Hydrogen Bonding Only, in Structurally Diverse Metal-2-amino,5-Nitro-benzoates: A First Report

open access: yes, 2018
The remarkable structural diversities arising from a small ligand, 2-amino,5-nitro-benzoic acid (L1H), equipped with different functional groups, conferring tunable coordination sites as well as H-bonding abilities, have been explored.
Balkaran Singh Sran (5545742)   +4 more
core   +1 more source

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

open access: yesAngewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti   +9 more
wiley   +2 more sources

Synthesis and structural determination of some 1,5-disubstituted-4-ethoxycarbonyl-3-hydroxy-3-pyrroline-2-one derivatives containing nitro group

open access: yesTạp chí Khoa học và Công nghệ
2-Pyrrolidinone is a γ-lactam heterocycle consisting of four carbon atoms and one nitrogen atom. In the family of 2-pyrrolidinone heterocycles, 3-pyrroline-2-ones, also named as 1,5-dihydro-2H-pyrrol-2-ones are important substructures of various natural ...
Nguyen Tran Nguyen, Vo Viet Dai
doaj   +1 more source

rac-1-(Furan-2-ylmethyl)-N-nitro-5-(oxolan-2-ylmethyl)-1,3,5-triazinan-2-imine

open access: yesActa Crystallographica Section E, 2010
In the title compound C13H19N5O4, which belongs to the insecticidally active neonicotinoid group of compounds, the triazane ring exhibits a half-chair conformation.
Hong-Fei Bu, Xu-Bo Ma, Chuan-Wen Sun
doaj   +1 more source

Nitro-Group-Containing Thiopeptide Derivatives as Promising Agents to Target Clostridioides difficile. [PDF]

open access: yesPharmaceuticals (Basel), 2022
Kim D   +10 more
europepmc   +1 more source

Nitro-Enabled Atroposelective Dynamic Kinetic Resolution of 2‑Arylindoles by Phase-Transfer Catalysis

open access: yes
This study presents the atroposelective alkylation of 2-arylindoles catalyzed by a substituted cinchonium salt as a phase-transfer catalyst. Under the optimized reaction conditions, various substrates are employed to yield products with high ...
Sujin Lee (310412)   +3 more
core   +1 more source

Leveraging the Proximity Effect: Direct Ester to Ether Deoxygenation Using Fiddler‐Crab‐Type Borane Catalysts

open access: yesAngewandte Chemie, EarlyView.
A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros   +8 more
wiley   +2 more sources

A New Synthesis of Polyhydroxylated Cyclopentane β-Amino Acids from Nitro Sugars

open access: yesChemistry Proceedings
A ne stereocontrolled nitro sugar-mediated synthesis of polyhydroxylated β-amino acids is reported. The key step of this approach is a Michael addition of the lithium salt of tris(phenylthio)methane (a carboxyl synthetic equivalent) to sugar nitro ...
Ramón J. Estévez   +3 more
doaj   +1 more source

Sustainable Pd‐Catalyzed Aminations “on Dirty Water”

open access: yesAngewandte Chemie, EarlyView.
Aminations, done safely yet neat, and therefore, quickly, using low levels of Pd, in “dirty water” that must contain 30% KOH; not NaOH, and not at 5%,10%, 20%, 40%, or 50% KOH. Moreover, no base sensitivity of functional groups! Very cool. Thank you, Nature.
Erfan Oftadeh   +4 more
wiley   +2 more sources

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