Results 121 to 130 of about 106,125 (294)

Crystal packing of two 5-substituted 2-methyl-4-nitro-1H-imidazoles

open access: yes, 2007
Infinite chains connected by N-H...N hydrogen bonding form the primary packing motif in two closely related 4-nitroimidazole derivatives, viz. 5-bromo-2-methyl-4-nitro-1H-imidazole, C4H4BrN3O2, (I), and 2-methyl-4-nitro-1H-imidazole-5-carbonitrile ...
Maciej Kubicki (832465)   +2 more
core  

Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges

open access: yesAngewandte Chemie International Edition, EarlyView.
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley   +1 more source

Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide

open access: yesActa Crystallographica Section E: Crystallographic Communications
An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the
Pawan Dhote   +2 more
doaj   +1 more source

Nitro group as a new anchoring group for organic dyes in dye-sensitized solar cells

open access: yes, 2012
An organic dye JY1 bearing a nitro group was designed, synthesized and applied in DSCs. An unusual colour change was observed when the voltage applied to the device was reversed which was accompanied by a five-fold increase in the cell efficiency.
Liu, Jing,   +6 more
core   +1 more source

Conformation preference of 5-nitro group in 1,3-dioxanes [PDF]

open access: yes, 1975
1. The protonation of the 2-phenyl-5-nitro-1,3-dioxane anion with water leads via equatorial attack to the cis-isomer. 2. 2-Aryl-5-nitro-1,3-dioxanes have a cis-configuration with an axial NO2 group. 3.
Arbuzov B.   +3 more
core  

New inhibitors of bacterial hyaluronidase - synthesis and structure-activity relationships

open access: yes, 2006
Potent and selective inhibitors of hyaluronidases are not reported in the literature so far. Such compounds are required as pharmacological tools to investigate the physiological and pathophysiological role of the enzymes and their preferred substrate ...
Braun, Stephan
core   +1 more source

Nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) in the environment – A review

open access: yes, 2017
Nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) are derivatives of PAHs with at least one nitro-functional group (-NO2) on the aromatic ring. The toxic effects of several nitro-PAHs are more pronounced than those of PAHs.
Bandowe, B.   +3 more
core   +1 more source

A new reagent for selective reduction of nitro group

open access: yes, 2009
1315-1318The nitro group in aromatic nitro compounds containing reducible substituents such as methyl, carboxylic acids and phenols, and halogens are selectively and rapidly reduced at room temperature to the corresponding amines in good yield by ...
Raju, B, Sivasankar, B N, Ragul, R
core  

Relaxed structure of typical nitro explosives in the excited state: observation, implication and application

open access: yes, 2017
Understanding the structural, geometrical and chemical changes that occur after electronic excitation is essential to unraveling the inherent mechanism of nitro explosives. In this work, relaxed structures of typical nitro explosives in the excited state
Weihua, He   +9 more
core   +1 more source

Quantum-chemical study of nucleophilic substitution of nitro group in N-alkyl-3-nitro-1,2,4-triazoles molecules in reactions with alicyclic alcohols and polyatomic phenols

open access: yesЖурнал Белорусского государственного университета: Химия, 2018
Nucleophilic substitution of nitro group in N-alkyl-3-nitro-1,2,4-triazoles molecules with alicyclic alcohols (cyclohexanol, menthol) and polyatomic phenols (pyrocatechol, resorcinol) in the gas phase and in aqueous solution was studied by means of ...
Vadim E. Matulis   +4 more
doaj  

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