Results 161 to 170 of about 130,387 (339)

Hydrogen Isotope Exchange in Pyridine Catalyzed by an Iron(II) Imido Complex: Counterion‐Directed Regioselectivity

Angewandte Chemie, EarlyView.
Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng, Guorong Li, Yafei Gao, Nobuyuki Yamamoto, Maren Pink, Qian Peng, Jeremy M. Smith   +6 more
wiley   +2 more sources

Reconstructing breastfeeding and weaning practices in the Bronze Age Near East using stable nitrogen isotopes. [PDF]

Am J Phys Anthropol, 2020
Stantis C, Schutkowski H, Sołtysiak A.
europepmc   +1 more source

Mn‐Induced Support Stabilization and Ir Electronic Activation Enable Acid‐Stable, Low‐Loading IrO2 Water Oxidation

Advanced Science, EarlyView.
This study introduces a dual‐regulation strategy utilizing a Mn‐doped Co3O4 support to enhance the activity and stability of low‐loading IrO2 catalysts for acidic water oxidation. Mn induces strong Mn─O covalency to reinforce the spinel lattice and activates Ir sites via interfacial electron transfer.
Zhe Liu, Guoxin Ma, Shixiang Yu, Rui Jin, Fei Wang, Xinxin Wen, Mengxin Chen, Yani Ding, Jia Liu, Xinkai Guo, Diab Khalafallah, Hassan Fouad, Xiao Ren, Siwei Li   +13 more
wiley   +1 more source

Programming Palladium Cage Geometry through Ligand Redox Modulation

Angewandte Chemie, EarlyView.
A neutral redox‐active exTTF ligand (L) forms a Pd2L4 cage, whereas its oxidized form (Lox) yields a Pd2(Lox)2 macrocycle. Lox further assembles with a dibenzothiophene derivative (L′) into Pd2(Lox)(L′)2 and Pd4(Lox)4(L′)4 architectures. Reduction of Pd2(Lox)2 and Pd2(Lox)(L′)2 restores the parent Pd2L4 cage, enabling redox controlled nuclearity ...
Jennifer Bou Zeid, Jean Nicolas, Maksym Dekhtiarenko, David Canevet, Magali Allain, Vincent Carré, Frédéric Aubriet, Laura Neukirch, Elie Benchimol, Marc Sallé, Guido H. Clever, Sébastien Goeb   +11 more
wiley   +2 more sources

Determining nitrogen isotopes discrimination under drought stress on enzymatic activities, nitrogen isotope abundance and water contents of Kentucky bluegrass. [PDF]

Sci Rep, 2020
Saud S, Fahad S, Cui G, Yajun C, Anwar S, Anwar S.   +5 more
europepmc   +1 more source

Main‐Chain Ion‐Pair Polybenzimidazole Membranes Enabling Reduced‐Temperature HT‐PEMFC Operation (Down to 120°C)

Advanced Energy Materials, EarlyView.
Embedding imidazolium‐biphosphate ion pairs directly into the polybenzimidazole main chain simultaneously stabilizes phosphoric acid and preserves continuous proton transport pathways. Strong ion‐pair and hydrogen‐bond interactions suppress acid leaching while maintaining high conductivity, enabling stable and durable high‐temperature fuel cell ...
Huina Lin, Brian C. Benicewicz
wiley   +1 more source

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

Angewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang, Yang Liu, Menghao Kong, Shilong Li, Shizhe Liu, Guanjie He, Shuyan Gao   +6 more
wiley   +2 more sources

Raw data for needle nitrogen and carbon level and isotopic compositions of the Picea neoveitchii tree and for soil nutrients in mountain areas of western Hubei province, central China

, 2019
Mao‐Chang Liang, Fei Fei, Wei Tang, Fujun Gong, Bing Sun, Yujie Yang, Die Hu   +6 more
openalex   +1 more source

Shell-model study of boron, carbon, nitrogen, and oxygen isotopes with a monopole-based universal interaction [PDF]

, 2012
Cenxi Yuan, Toshio Suzuki, Takaharu Otsuka, F. R. Xu, Naofumi Tsunoda   +4 more
openalex   +1 more source

Topology‐Aware Machine Learning for High‐Throughput Screening of MOFs in C8 Aromatic Separation

Advanced Intelligent Discovery, EarlyView.
We screened 15,335 Computation‐Ready, Experimental Metal–Organic Frameworks (CoRE‐MOFs) using a topology‐aware machine learning (ML) model that integrates structural, chemical, pore‐size, and topological descriptors. Top‐performing MOFs exhibit aromatic‐enriched cavities and open metal sites that enable π–π and C–H···π interactions, serving as ...
Yu Li, Honglin Li, Jialu Li, Wan‐Lu Li
wiley   +1 more source