Results 91 to 100 of about 2,273 (210)
ABSTRACT Subalpine conifers such as Abies koreana E.H.Wilson (Korean fir) play a significant ecological role but are increasingly endangered due to the effects of climate change, including the high prevalence of insect pests. This study identified for the first time, a notorious aphid pest on newly developed needles and twigs of A.
Su‐In Choi +8 more
wiley +1 more source
Kinetic Isotope effect (KIE) measurements are a powerful tool to interrogate enzyme mechanisms and transition state structures. In this study, we develop a simple quantitative MALDI‐TOF mass spectrometry approach to measure competitive heavy atom KIEs.
Teodora Kljaic +5 more
wiley +1 more source
OBJECTIVE: To standardize a technique for ventilating rat fetuses with Congenital Diaphragmatic Hernia (CDH) using a volume-controlled ventilator. METHODS: Pregnant rats were divided into the following groups: a) control (C); b) exposed to nitrofen ...
Rodrigo Melo Gallindo +4 more
doaj +1 more source
We present a rapid, operationally simple, and broadly applicable protocol for the catalytic formation and in situ electrochemical characterization of chiral a,b‐unsaturated iminium ions by cyclic voltammetry (CV). Using only 5 mol% of the aminocatalyst, we systematically measure the reduction potential of over 50 iminium intermediates, revealing how ...
Martí Gisbert +2 more
wiley +1 more source
Asymmetric Michael addition of cyanide to α,β‐unsaturated aldehydes catalyzed by diarylmethyl‐substituted diphenylprolinol silyl ethers:Thermodynamically controlled product formation under kinetic enantioselective catalysis. Diphenylprolinol silyl ether catalyzed asymmetric Michael/1,2‐addition reaction of cyanide to α,β‐unsaturated aldehydes at high ...
Konstantinos Daskalakis +4 more
wiley +1 more source
Metal‐Dependent Effects and Crowding Robustness of Pseudomonas fluorescens Esterase I
Pseudomonas fluorescens esterase I retains catalytic activity in metal‐rich and crowded environments, despite metal‐specific inhibitory effects. These findings highlight its robustness for biocatalytic applications in complex environments. Industrial biocatalysts are strongly influenced by their physicochemical environment, yet systematic studies on ...
Emmanouil Ntermanakis +6 more
wiley +1 more source
Fine particle (PM2.5) controls in China have achieved great success these years, but heavy haze pollution still occurs occasionally. The sources and evolution of the complex organic mixtures remain poorly resolved.
Xuehui He +17 more
doaj +1 more source
Humans are exposed to various bisphenols, alkylphenols and nitrophenols through dietary intake, food packaging and container materials, indoor and outdoor air/dust. This study aimed to evaluate exposure of Japanese pregnant women to environmental phenols
Neeranuch Suwannarin +3 more
doaj +1 more source
Semi‐rational engineering yields a thermostable Bacillus simplex formate dehydrogenase variant (Q125F) with a 25‐fold longer half‐life at 60°C and strong resistance to chemo‐inactivation. Molecular dynamics reveal enhanced π–π interactions stabilizing a flexible loop and enabling efficient NADH regeneration for robust biocatalytic detoxification ...
Rattima Boonkumkrong +7 more
wiley +1 more source

