Results 91 to 100 of about 2,273 (210)

Identification and Biocontrol of Mindarus japonicus Takahashi, a New Pest of Abies koreana E.H.Wilson Using Bacillus velezensis CE 100

open access: yesEntomological Research, Volume 56, Issue 7, July 2026.
ABSTRACT Subalpine conifers such as Abies koreana E.H.Wilson (Korean fir) play a significant ecological role but are increasingly endangered due to the effects of climate change, including the high prevalence of insect pests. This study identified for the first time, a notorious aphid pest on newly developed needles and twigs of A.
Su‐In Choi   +8 more
wiley   +1 more source

Direct Competitive Kinetic Isotope Effect Measurement Using Quantitative Whole Molecule Matrix‐Assisted Laser Desorption Ionization Time‐of‐Flight Mass Spectrometry

open access: yesChemBioChem, Volume 27, Issue 12, 26 June 2026.
Kinetic Isotope effect (KIE) measurements are a powerful tool to interrogate enzyme mechanisms and transition state structures. In this study, we develop a simple quantitative MALDI‐TOF mass spectrometry approach to measure competitive heavy atom KIEs.
Teodora Kljaic   +5 more
wiley   +1 more source

Standardization of pulmonary ventilation technique using volume-controlled ventilators in rats with congenital diaphragmatic hernia

open access: yesRevista do Colégio Brasileiro de Cirurgiões
OBJECTIVE: To standardize a technique for ventilating rat fetuses with Congenital Diaphragmatic Hernia (CDH) using a volume-controlled ventilator. METHODS: Pregnant rats were divided into the following groups: a) control (C); b) exposed to nitrofen ...
Rodrigo Melo Gallindo   +4 more
doaj   +1 more source

Redox Properties of Catalytically Generated Iminium Ions From α,β‐Unsaturated Aldehydes and Chiral Secondary Amines

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 24, 23 June 2026.
We present a rapid, operationally simple, and broadly applicable protocol for the catalytic formation and in situ electrochemical characterization of chiral a,b‐unsaturated iminium ions by cyclic voltammetry (CV). Using only 5 mol% of the aminocatalyst, we systematically measure the reduction potential of over 50 iminium intermediates, revealing how ...
Martí Gisbert   +2 more
wiley   +1 more source

Asymmetric Michael Addition of Cyanide to α,β‐Unsaturated Aldehydes Catalyzed by Diarylmethyl‐Substituted Diphenylprolinol Silyl Ethers: Thermodynamically Controlled Product Formation under Kinetic Enantioselective Catalysis

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
Asymmetric Michael addition of cyanide to α,β‐unsaturated aldehydes catalyzed by diarylmethyl‐substituted diphenylprolinol silyl ethers:Thermodynamically controlled product formation under kinetic enantioselective catalysis. Diphenylprolinol silyl ether catalyzed asymmetric Michael/1,2‐addition reaction of cyanide to α,β‐unsaturated aldehydes at high ...
Konstantinos Daskalakis   +4 more
wiley   +1 more source

Metal‐Dependent Effects and Crowding Robustness of Pseudomonas fluorescens Esterase I

open access: yesChemBioChem, Volume 27, Issue 11, 15 June 2026.
Pseudomonas fluorescens esterase I retains catalytic activity in metal‐rich and crowded environments, despite metal‐specific inhibitory effects. These findings highlight its robustness for biocatalytic applications in complex environments. Industrial biocatalysts are strongly influenced by their physicochemical environment, yet systematic studies on ...
Emmanouil Ntermanakis   +6 more
wiley   +1 more source

The significant contribution of biomass burning to methanol-soluble nitrogenous organics and its evolution during the highly-humid haze event in urban Wuhan

open access: yesnpj Climate and Atmospheric Science
Fine particle (PM2.5) controls in China have achieved great success these years, but heavy haze pollution still occurs occasionally. The sources and evolution of the complex organic mixtures remain poorly resolved.
Xuehui He   +17 more
doaj   +1 more source

Urinary concentrations of environmental phenol among pregnant women in the Japan Environment and Children’s Study

open access: yesEnvironment International
Humans are exposed to various bisphenols, alkylphenols and nitrophenols through dietary intake, food packaging and container materials, indoor and outdoor air/dust. This study aimed to evaluate exposure of Japanese pregnant women to environmental phenols
Neeranuch Suwannarin   +3 more
doaj   +1 more source

Semi‐Rational Engineering of Formate Dehydrogenase Reveals Loop Dynamics as a Key Determinant of Thermostability

open access: yesChemBioChem, Volume 27, Issue 11, 15 June 2026.
Semi‐rational engineering yields a thermostable Bacillus simplex formate dehydrogenase variant (Q125F) with a 25‐fold longer half‐life at 60°C and strong resistance to chemo‐inactivation. Molecular dynamics reveal enhanced π–π interactions stabilizing a flexible loop and enabling efficient NADH regeneration for robust biocatalytic detoxification ...
Rattima Boonkumkrong   +7 more
wiley   +1 more source

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