Toward Reliable Spectroscopic Analysis of Reaction Kinetics in Polaritonic Chemistry
Vibrational strong coupling has been reported to modify chemical reaction rates, yet its mechanism remains unresolved. We expose pitfalls in UV/Vis‐based kinetic analyses and emphasize the need for standardized cavity protocols. ABSTRACT Recent reports suggest that chemical reaction rates can change inside an optical cavity.
Robrecht M. A. Vergauwe +2 more
wiley +1 more source
Glycomimetics with triazoline and aziridine groups were synthesised via diastereoselective Huisgen cycloaddition from glycosyl azides. Density functional theory was applied to define the mechanism for BF3 promoted aziridine formation. Triazoline and aziridine derivatives were synthesised by diastereo‐ and regioselective Huisgen cycloaddition of 2,3,4,6‐
Aaron McCormack +4 more
wiley +1 more source
Exploring Diverse Glycone Preferences of Aspergillus rutinosidases
Rutinosidases from Aspergillus niger (AnRut) and A. oryzae (AoRut) catalyze hydrolysis and transglycosylation with non‐natural glycosides as donors, enabling glycosylation of alcoholic and phenolic acceptors. AnRut exhibits broad glycone promiscuity, while AoRut has a narrower substrate scope.
Jitka Brouzdová +9 more
wiley +1 more source
Utilization of 2-nitrophenols in annulations with aryl isothiocyanates towards the synthesis of 2-aminobenzoxazoles. [PDF]
Nguyen TD +4 more
europepmc +1 more source
Studies on the polarogrphic behaviour of nitrophenols
Phadke, RS, Subrahmanya, RS
openaire +2 more sources
Dimethylammonium 4-nitrophenolate–4-nitrophenol (1/1)
The title compound, C2H8N+·C6H4NO3−·C6H5NO3, was synthesized from dimethylamine and 4-nitrophenol in an overall yield of 85%. The dihdral angles between the nphenyl rings and their attached nitro groups are 5.7 (6) and 2.5 (7)°. In the crystal, there are strong hydrogen bonds between the ammonium
openaire +1 more source
A novel MOF-based electrochemical sensor for simultaneous quantification of nitrophenols in binary mixtures using artificial neural networks: challenges and opportunities. [PDF]
Kiasadr A, Sajjadi SM, Baghayeri M.
europepmc +1 more source
Reliable p<i>K</i><sub>a</sub> Prediction through Efficient Incorporation of Anharmonicity within the Nuclear-Electronic Orbital Framework. [PDF]
Yoo JM +3 more
europepmc +1 more source
Continuous-Flow Microreactor System for Enhanced Selectivity and Safety in Nitrobenzene Nitration. [PDF]
Zhao W, Wang S, Zhao W, Wei W, Yan D.
europepmc +1 more source

