Partial Dissociation and Hydration Quantitatively Explain the Properties of Aqueous Electrolyte Solutions and hence Empirical Activity Concepts are Unnecessary [PDF]
The author shows that Arrhenius's theory of partial electrolytic dissociation was immaturely displaced about eight decades ago by the empirical concept of ionic activities and the assumption of complete dissociation of electrolytes at all ...
Raji Heyrovska
core +1 more source
Analytical interfacial layer model for the capacitance and electrokinetics of charged aqueous interfaces [PDF]
We construct an analytical model to account for the influence of the subnanometer-wide interfacial layer on the differential capacitance and the electro-osmotic mobility of solid–electrolyte interfaces.
Bonthuis, Douwe Jan +2 more
core +2 more sources
For the first time, a highly sensitive electrochemical biosensor based on SiO2‐based hairy particles with a grafted PDMAEMA polymer brush containing a quantifiable and large amount of immobilized Laccase is reported. The fabricated biosensor exhibits a sensitivity of 0.14 A·m⁻¹, a limit of detection (LOD) of 0.1 µm, and a detection range of 0.3–750 µm,
Pavel Milkin +7 more
wiley +1 more source
The properties of electrolyte solutions in nonaqueous and mixed solvents [PDF]
This paper constitutes a reviev of the results of investigations on electrolyte solutions in some organic solvents that behaves similarly to water from thermochemical point of vi,»w as well as in some water - organic mixed solvents.
Piekarski, Henryk +1 more
core
Electroactive Metal–Organic Frameworks for Electrocatalysis
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska +7 more
wiley +1 more source
Titanium surfaces were anodized to create nanotube structures utilizing an aqueous electrolyte made of xanthan gum (XG) and sodium fluoride. The purpose of employing this type of anodizing solution was to investigate the impact of XG addition on the ...
Robinson Aguirre Ocampo +1 more
doaj +1 more source
A new inorganic atmospheric aerosol phase equilibrium model (UHAERO) [PDF]
A variety of thermodynamic models have been developed to predict inorganic gas-aerosol equilibrium. To achieve computational efficiency a number of the models rely on a priori specification of the phases present in certain relative humidity regimes ...
Amundson, N. R. +6 more
core +2 more sources
X-ray photoelectron spectroscopy investigation of nanoporous NiO electrodes sensitized with Erythrosine B [PDF]
Nanoporous NiO thin films were prepared onto FTO glass substrates by means of screen-printing and were sensitized with Erythrosine B (EryB) dye. The obtained material was electrochemically treated and characterized with ex-situ X-ray photoelectron ...
BONOMO, MATTEO +3 more
core +1 more source
3D‐Printed Sulfur‐Derived Polymers With Controlled Architectures for Lithium‐Sulfur Batteries
Rheology‐guided formulation design for direct ink writing enables the fabrication of 3D sulfur copolymer cathodes with controlled architectures for lithium‐sulfur batteries. The printed electrodes exhibit multiscale porosity and high sulfur utilization, delivering enhanced electrochemical performance compared to conventional cast electrodes.
Bin Ling +7 more
wiley +1 more source
High Voltage Redox-Meditated Flow Batteries with Prussian Blue Solid Booster
This work presents Prussian blue solid boosters for use in high voltage redox-mediated flow batteries (RMFB) based on non-aqueous electrolytes. The system consisted of sodium iodide as a redox mediator in an acetonitrile catholyte containing solid ...
John Ostrander +2 more
doaj +1 more source

