Results 221 to 230 of about 26,195 (294)

Nanocubes and Cuboctahedra: Entropic Stabilization Versus Thermal Segregation in Rock Salt‐ and Spinel‐Type Multinary Oxides from Spray‐Flame Synthesis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Spray‐flame synthesis enables highly flexible and scalable production of multinary and high‐entropy oxide nanoparticles due to high synthesis temperatures with subsequent quenching. Temperature‐dependent in situ diffraction of as‐synthesized materials clearly reveals entropy stabilization in rock salt lattices, while spinels—featuring tetrahedral and ...
Mohammed‐Ali Sheikh   +7 more
wiley   +1 more source

Interfacial Charge‐Transfer Enhancement via High‐Entropy Alloy Regulated MXene Heterostructures for Asymmetric Supercapacitor Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel core‐shell HEA@MXene composite was synthesized to enhance supercapacitor electrochemistry. DFT simulations reveal the role of HEA doping in regulating the MXene interface. The HEA@MXene composite exhibits a high specific capacitance of 872 F g−1 at 1 A g−1 with remarkable stability in 1 M KOH.
Fenhong Song   +8 more
wiley   +1 more source

Hydroxylated MXene‐Assisted In Situ Synthesis of Ultrafine CoHCC Nanoparticles for High‐Performance Potassium‐Ion Battery Anodes

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study develops hydroxylated MXene‐supported ultrafine cobalt hexacyanocobaltate anodes through interfacial engineering, achieving enhanced conductivity, structural stability, and superior potassium‐ion storage performance. Cobalt‐based Prussian blue analogs (CoHCC) have emerged as highly promising anode materials for potassium‐ion batteries due to
Anni Chen   +6 more
wiley   +1 more source

Fluorescence Behavior of Water‐Soluble Porphyrins Immobilized on LTA Zeolite and Its Chlorogenic Acid Polyphenol Sensing in Coffee Wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
During coffee bean and cherry washing, contaminants are released into water, making this process a major source of water pollution. Chlorogenic acid can be efficiently detected using hybrid zeolite–porphyrin materials by measuring fluorescence quenching, achieving detection limits lower than current regulatory thresholds.
João Otávio Donizette Malafatti   +10 more
wiley   +1 more source

Unveiling Strain‐Driven Catalysis in Magnesium Hydride via Ultrafine High‐Entropy Hydride

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The unprecedented, direct, and tailored synthesis of high‐entropy hydride (HEH) nanoparticles is achieved under ambient conditions via one‐step mechanochemical strategy and demonstrates exceptional catalytic behaviors in magnesium hydride (MgH2) hydrogen storage, where partially dehydrogenated HEH introduces abundant lattice strain and hydrogen ...
Jiaguang Zheng   +6 more
wiley   +1 more source

Imidazolium Modified UiO‐67 Metal‐Organic Frameworks for CO2 Adsorption

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
CO2 sorption in UiO‐67 and its imidazolium‐functionalized derivatives is examined with emphasis on the role of different counterions. Structural characterization and spectroscopic studies provide insight into how functionalization affects pore environments and CO2 interactions.
Lisa Eisele   +6 more
wiley   +1 more source

Anion Exchange Pathways in Half‐Heusler‐Type Holmium Hydride Oxide HoHO

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The oxidation of half‐Heusler‐type holmium hydride oxide HoHO in air is tracked by in situ neutron powder diffraction, revealing Ho2H0.50O2.75 as the holmium analogue of the Y2H0.50O2.75 intermediate in YHO. Despite nearly identical ionic radii and closely related intermediate structures, the holmium system shows a narrower stability range and faster ...
Marvin Michak, Holger Kohlmann
wiley   +1 more source

Cyclodextrins as Chiral Selectors in Capillary Electrophoresis—Recent Developments in Understanding Analyte Complexation and Applications in Pharmaceutical Analysis

open access: yesELECTROPHORESIS, EarlyView.
Cyclodextrins are the most often applied chiral selectors in CE enantioseparations. In combination with NMR spectroscopy and molecular modeling, studies for an understanding of chiral recognition underlying enantioseparations have been performed.
Gerhard K. E. Scriba
wiley   +1 more source

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