Results 121 to 130 of about 48,033 (274)
Two‐Dimensional Layered Hydroxide Materials for Nucleophile Oxidation
ChemElectroChemThe global energy crisis highlights the need to transition from fossil fuels to sustainable, renewable sources of energy. Green hydrogen produced via renewable energy‐driven water electrolysis is an emerging alternative due to its zero emissions and high
Yuwei Yang, Dr. Nicholas M. Bedford
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Angewandte Chemie, EarlyView.Catalytic, intramolecular N‐heterocycle arylation by nucleophilic aromatic substitution (SNAr) is now available for synthesis of highly strained macrocycles and medium‐sized heterobiaryl atropisomeric rings, including atropopeptides. Key to the approach is the ability to generate a strong base catalytically, taking advantage of base‐embedding ...
Alireza Abbasi Kejani +7 more
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Nature CommunicationsCarbon-silicon-switch strategy, replacing one specific carbon atom in organic molecules with a silicon, has garnered significant interest for developing new functional molecules.
Yu Yan +5 more
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Peptide splicing in the proteasome : a minimal size requirement for the nucleophile peptide
, 2014 Peptide splicing in the proteasome : a minimal size requirement for the nucleophile ...
Vigneron, Nathalie +1 more
core
Z‐Retentive Enantioselective Rh‐Catalyzed Hydroarylation of E,Z‐Dienes
Angewandte Chemie, EarlyView.The Rh‐catalyzed hydroarylation of conjugated E,Z‐dienoates is found to proceed with high selectivity for addition to the E‐alkene unit. Mechanistic analysis of this Z‐retentive process points towards preferred binding of the E‐alkene unit to a Rh‐aryl species to give rise to the observed selectivity and that Rh‐enolate protonolysis to be turnover ...
Wesley McNutt +4 more
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Communications ChemistryInorganic pyrophosphatases are essential metalloenzymes for phosphate metabolism. Bacterial Family II Inorganic pyrophosphatases utilize a trinuclear metal center and exhibit higher catalytic activity than binuclear counterparts.
Saki Maruoka +10 more
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Bifunctional Asymmetric Catalysis: A Tandem Nucleophile/Lewis Acid Promoted Synthesis of β-Lactams
, 2016 We describe a superior procedure for the catalytic, asymmetric synthesis of β-lactams using a bifunctional catalyst system consisting of a chiral nucleophile and an achiral Lewis ...
Ahmed M. Hafez (2714233) +5 more
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ChemistryThis study investigated the acyl group transfer reactions of 2,4-dinitrophenyl 5-substituted-2-furoates, promoted by 4-substituted phenoxides/phenols in a 20 mol% DMSO aqueous solution at 25 °C.
Sang-Yong Pyun, Seung-Taek Hong
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Nature CommunicationsThe development of organo-catalyzed C(sp2)–O functionalization has gained significant importance in modern synthetic chemistry. However, a practical and general strategy for constructing chiral molecules via this approach remains elusive.
Jia-Le Zhang +6 more
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Multiple Isocyanide insertions promoted by protic and Lewis acids
Tetrahedron ChemThe protonation, or Lewis Acid complexation, of electrophiles can trigger the sequential insertion of two or more isocyanides resulting in valuable iminonitriles or heterocycles.
John Kornfeind, Fraser F. Fleming
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