Results 41 to 50 of about 9,130,114 (266)

Mechanistic Kinetic Analysis of Fast Pyrolysis of Vanillin to Primary Phenols

open access: yesFrontiers in Energy Research, 2022
Vanillin is a major fine chemical in the flavoring industry and one of the pyrolysates from lignin. In order to understand the primary decomposition pathways of vanillin, analytical fast pyrolysis experiments were performed in the temperature range of ...
Attada Yerrayya   +2 more
doaj   +1 more source

Integration of Spatiotemporal Multi‐Omics in Peach Fruit Unravels a Metabolic Niche and the Genetic Basis of Trichome‐Mediated Stress Adaptation

open access: yesAdvanced Science, EarlyView.
This study constructed the first spatiotemporal multi‐omics map of peach fruit and discovered a key candidate gene that synergistically regulates trichome development and drought tolerance through the jasmonic acid signaling pathway, providing insights into the coupling mechanism between development and stress resistance.
Zhixin Liu   +9 more
wiley   +1 more source

Whole-molecule disorder of the heterometallic complex diaqua-1κ2O-dichlorido-2κ2Cl-(μ-2-formyl-6-methoxyphenolato-1κ2O1,O2:2κO6){μ-2-methoxy-6-[(methylimino)methyl]phenolato-1κ2N,O1:2κO6}lead(II)nickel(II)

open access: yesActa Crystallographica Section E: Crystallographic Communications
The new molecular complex [NiPb(C9H10NO2)(C8H7NO3)Cl2(H2O)2] with the Schiff base 2-methoxy-6-[(methylimino)methyl]phenol and ortho-vanillin ligands, both deprotonated, crystallizes in the monoclinic space group P21/c with one molecule per asymmetric ...
Olga Yu. Vassilyeva   +2 more
doaj   +1 more source

Crystal structure of bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) 0.39-hydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, [Mn(C12H15NO5)2]·0.39H2O, is a 0.39 hydrate of the isostructural complex bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) that has previously been reported by Back, Oliveira, Canabarro ...
Elena A. Buvaylo   +2 more
doaj   +1 more source

Carboranyl‐Curcuminoids for the Neutron Capture‐Based Treatment of Amyloid Aggregates in Alzheimer's Disease

open access: yesAdvanced Science, EarlyView.
The 10B‐enriched monocarbonyl analog of curcumin (BMAC) 10B‐9 enables site‐specific Boron Neutron Capture Therapy (BNCT) on amyloid‐β (Aβ) fibrils. Neutron irradiation induces histidine oxidation and fibril destabilization, as revealed by 1H‐NMR and FESEM analyses.
Sebastiano Micocci   +13 more
wiley   +1 more source

Crystal structure of tetrakis(μ3-2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)tetrakis[aquacopper(II)]: a redetermination at 200 K

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The crystal structure of the tetranuclear title compound, [Cu4(C12H15NO5)4(H2O)4], has been previously reported by Back, Oliveira, Canabarro & Iglesias [Z. Anorg. Allg. Chem. (2015), 641, 941–947], based on room-temperature data.
Elena A. Buvaylo   +2 more
doaj   +1 more source

Senolytic Therapy as a Preventive Strategy for Spine Degeneration and Pain

open access: yesAdvanced Science, EarlyView.
Cellular senescence promotes inflammation, tissue degeneration, and chronic back pain. In sparc‐null mice, early oral administration of the senolytic agents o‐vanillin and RG‐7112 reduced senescent cell burden and pro‐inflammatory SASP signaling across intervertebral discs, endplates, vertebral bone, and spinal cord.
Saber Ghazizadeh   +7 more
wiley   +1 more source

Crystal structure of 4,10-dimethoxy-13-methyl-6H,12H-6,12-epiminodibenzo[b,f][1,5]dioxocine

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The title compound, C17H17NO4, lacks crystallographic symmetry with one molecule per asymmetric unit. The molecule exists in a folded butterfly-like conformation; the benzene rings form a dihedral angle of 84.72 (7)°.
Katerina V. Kasyanova   +4 more
doaj   +1 more source

A Novel CsYABBY3‐CsAS1 Feedback Loop Coordinates Trichome Differentiation and Cannabinoid Biosynthesis in Cannabis sativa L.

open access: yesAdvanced Science, EarlyView.
A novel transcriptional module involving CsYABBY3 and CsAS1 is identified to regulate cannabinoid biosynthesis and trichome development. These factors mutually activate each other and form a protein complex via a conserved residue, acting synergistically to amplify metabolic flux through a coordinate feed‐forward mechanism.
Xuewen Zhu   +18 more
wiley   +1 more source

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