Results 151 to 160 of about 14,737 (279)

Redox‐Dependent Luminescence in a Pentavalent Uranyl Complex

open access: yesChemistryEurope, EarlyView.
Redox‐dependent luminescence in a molecular pentavalent uranyl complex supported by a pyridine dipyrrolide pincer ligand is presented. Electrochemical and chemical reduction of the uranyl(VI) species provides a stable uranyl(V) complex that emits blue light from a high‐energy excited state. The anti‐Kasha emission is credited to the presence of “nested”
Leyla R. Valerio   +5 more
wiley   +1 more source

The Newly Discovered Pathway for Oxygen Evolution Reaction: In‐Situ/Operando Characterization Techniques for Catalyst Development

open access: yesCarbon Energy, EarlyView.
This study introduces a newly discovered oxide path mechanism (OPM) for the oxygen evolution reaction (OER), emphasizing the role of in‐situ and operando characterization techniques in unraveling catalyst behavior under realistic conditions. The integration of advanced spectroscopic methods provides new mechanistic insights for the design of highly ...
Rabia Khalid   +4 more
wiley   +1 more source

Electronic Modulation of Pt Nanoparticles Induced by Defective TiN Promotes Highly Efficient Hydrogen Evolution

open access: yesCarbon Energy, EarlyView.
A nonequilibrium high‐temperature shock method was used to load Pt nanoparticles onto nitrogen vacancy‐rich TiN, enabling strong EMSI modulation. The Pt@TiN‐VN catalyst shows high HER activity (15.99 A mgPₜ⁻¹ at 100 mV) and 60‐h stability. Nitrogen vacancies optimize charge transfer and Pt–H bonding, offering insights into defect‐engineered ...
Meiyue Li   +5 more
wiley   +1 more source

Fe‐Facilitated Deep Reconstruction of Ni3S2 Toward Superior Oxygen Evolution

open access: yesCarbon Energy, EarlyView.
In situ Raman spectroscopy combined with density functional theory (DFT) reveals that Fe substitution is able to facilitate the deep reconstruction of Ni3S2 into oxyhydroxides (DR‐(Ni,Fe)OOH), inducing a downshift in the energy band structure, optimizing oxygen‐containing intermediates adsorption, and thereby improving the performance of the oxygen ...
Zhihang Liu   +9 more
wiley   +1 more source

MnO<sub>2</sub>-Modified Carboxylated Graphene Oxide Nanocomposite for the Effective Extraction of Organochlorine Pesticides from Environmental Water Samples. [PDF]

open access: yesNanomaterials (Basel)
Shaker MA   +8 more
europepmc   +1 more source

Regulating Defect‐Coordinated Single‐Iron‐Atom Catalysts for Efficient Nitrate Reduction Reactions

open access: yesCarbon Energy, EarlyView.
This figure illustrates the ball‐and‐stick model of an asymmetric monatomic Fe─N2 catalyst and its catalytic process for converting nitrate to ammonia. Shown are the adsorption configurations of precursors and intermediates (NO3− → NO2− → NO → NH2OH → NH3) on the catalyst surface, where brown represents iron atoms, red represents oxygen atoms, dark ...
Xia Ma   +12 more
wiley   +1 more source

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